Measurements

Preparation for General Chemistry · Dr. Karmach

Dr. Karmach

By the end of this unit, you can…

  • Write and read numbers in scientific notation
  • Report measurements and results with the correct significant figures
  • Convert units with conversion factors, canceling units at each step
  • Use density as a conversion factor between mass and volume
  • Convert a temperature among °C, °F, and K, and handle a temperature difference
Dr. Karmach

Today's route 🗺️

  1. Scientific Notation
  2. Significant Figures
  3. The SI Unit System
  4. Dimensional Analysis
  5. Temperature Scales & Conversions
  6. Density as a Conversion Factor
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1 · Scientific Notation

Write numbers in scientific notation and read them back (the decimal's move sets the exponent's size and sign, the coefficient stays at 1 ≤ M < 10), and enter them on a calculator with EE.

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Numbers too big and too small to write out

Written out, chemistry's numbers are unreadable. Scientific notation writes each in a handful of characters: the digits once, then a power of ten carrying the size.

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Powers of ten: one decimal place per step

10³ = 1000 · 10² = 100 · 10¹ = 10 · 10⁰ = 1 · 10⁻¹ = 0.1 · 10⁻² = 0.01 · 10⁻³ = 0.001
each step up multiplies by ten · each step down divides by ten

A positive exponent counts the zeros after the 1. A negative exponent means a number smaller than 1, never a negative number.

Write 10,000 and 0.00001 as powers of ten.

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Powers of ten: one decimal place per step

10³ = 1000 · 10² = 100 · 10¹ = 10 · 10⁰ = 1 · 10⁻¹ = 0.1 · 10⁻² = 0.01 · 10⁻³ = 0.001
each step up multiplies by ten · each step down divides by ten

A positive exponent counts the zeros after the 1. A negative exponent means a number smaller than 1, never a negative number.

Write 10,000 and 0.00001 as powers of ten.

10,000 = 10⁴ · 0.00001 = 10⁻⁵
a 1 followed by four zeros → 4 · the 1 sits five places right of the point → −5
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One coefficient, one exponent

Scientific notation writes any number as a coefficient times a power of ten: the coefficient carries the digits, the exponent carries the size.

6.022 × 10²³
coefficient M with 1 ≤ M < 10 · exponent n is a whole number · 10²³ = "times ten, 23 times"

Exactly one nonzero digit stands before the decimal point.

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Standard → scientific: count the decimal's move

Slide the decimal until one nonzero digit leads. Each factor of ten moves it one place, so places moved = factors of ten = the exponent n. Direction sets the sign.

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The method: convert to scientific notation

  1. Place the decimal so one nonzero digit leads: that is M.
  2. Count the places moved: that is |n|.
  3. Sign: left → add the places to n; right → subtract them.
  4. Write M × 10ⁿ.
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One map for every conversion

A plain number runs Steps 1 to 4. A calculator display already reads M × 10ⁿ. A coefficient worked out by hand that lands outside 1 to 10 goes back through Steps 1 to 3.

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Guided example: the radius of a gold atom

0.000000000166 m
given: radius of one gold atom · wanted: the same length as M × 10ⁿ m

A gold atom's radius is about 0.000000000166 m. Written out, the zeros hide the size.

Write the radius in scientific notation.

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Guided example: solution

0.000000000166 m
given: radius of one gold atom · wanted: M × 10ⁿ m

Step 1 · Place the decimal so one nonzero digit leads

The first nonzero digit is the 1. The decimal moves to sit just after it: M = 1.66.

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Guided example: solution

0.000000000166 m
given: radius of one gold atom · wanted: M × 10ⁿ m
Step 1 · Place the decimal so one nonzero digit leads Step 2 · Count the places moved

The point passes nine zeros and then the 1.

0.000000000166 → 1.66 · 9 zeros + 1 digit = 10 places
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Guided example: solution

0.000000000166 m
given: radius of one gold atom · wanted: M × 10ⁿ m
Step 1 · Place the decimal so one nonzero digit leads Step 2 · Count the places moved
0.000000000166 → 1.66 · 9 zeros + 1 digit = 10 places
Step 3 · Sign

The radius is less than 1 m, so the decimal moved right: n = −10.

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Guided example: solution

0.000000000166 m
given: radius of one gold atom · wanted: M × 10ⁿ m
Step 1 · Place the decimal so one nonzero digit leads Step 2 · Count the places moved
0.000000000166 → 1.66 · 9 zeros + 1 digit = 10 places
Step 3 · Sign Step 4 · Write M × 10ⁿ
0.000000000166 m = 1.66 × 10⁻¹⁰ m
Dr. Karmach

Guided example: solution

0.000000000166 m
given: radius of one gold atom · wanted: M × 10ⁿ m
Step 1 · Place the decimal so one nonzero digit leads Step 2 · Count the places moved
0.000000000166 → 1.66 · 9 zeros + 1 digit = 10 places
Step 3 · Sign Step 4 · Write M × 10ⁿ
0.000000000166 m = 1.66 × 10⁻¹⁰ m
An atom is far smaller than 1 m, so a large negative exponent fits. All three digits, 1, 6 and 6, stay in M. ✓
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Guided example: the route on the map

0.000000000166 m = 1.66 × 10⁻¹⁰ m
given: radius of one gold atom · found: M = 1.66 · n = −10

A plain number below 1: the decimal moves right, so the places come off n. ✓
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Practice 1

Earth to Sun: 149,600,000 km
given: 149,600,000 km · wanted: n in M × 10ⁿ km

The Sun sits 149,600,000 km from Earth. Written in scientific notation, what is the exponent n?

  1. −8
  2. 8
  3. 5
  4. 7
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Practice 1: answer B

149,600,000 km = 1.496 × 10⁸ km
M = 1.496 · decimal moves 8 places left · number > 1 → n = +8

B: the point moves left past 4, 9, 6 and five zeros, 8 places. A flipped the sign: a number above 1 takes a positive n. C counted only the five zeros and skipped 4, 9 and 6. D stopped one place early: 14.96 × 10⁷ leaves two digits before the point.

10⁸ is 100,000,000, and 149,600,000 is about 1.5 of those. ✓
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Practice 1: the route on the map

149,600,000 km = 1.496 × 10⁸ km
given: 149,600,000 km · found: n = 8

A plain number above 1: the decimal moves left, so the places add to n. ✓
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Worked example 1: two conversions

0.00456 and 93,000,000
write each in scientific notation, M × 10ⁿ

One is small (less than 1), one is large (greater than 1). Count the decimal's move for each, then read the sign from the direction.

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Worked example 1: solution

The small number moves right (negative n); the large number moves left (positive n).

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Worked example 1: solution

The small number moves right (negative n); the large number moves left (positive n).

0.00456 = 4.56 × 10⁻³
93,000,000 = 9.3 × 10⁷
3 places right → n = −3 · 7 places left → n = +7
A leading zero forces n negative; a long tail of zeros forces n positive.
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Worked example 1: the route on the map

0.00456 = 4.56 × 10⁻³ · 93,000,000 = 9.3 × 10⁷
given: two plain numbers · found: n = −3 and n = +7

Same steps for both numbers. Only Step 3 differs: right for the small one, left for the large one. ✓
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Scientific → standard: move the decimal back

Reverse it: the exponent says how many places to slide the decimal, and its sign says which way. Positive → right (bigger); negative → left (smaller).

9.3 × 10⁷ → 93,000,000 · 4.56 × 10⁻³ → 0.00456
+7: shift right 7 places, filling zeros · −3: shift left 3 places
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Your turn: convert 0.00072

Fill each blank, then check.

step value
coefficient M
decimal moves
exponent n
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Your turn: convert 0.00072

Fill each blank, then check.

step value
coefficient M
decimal moves
exponent n
0.00072 = 7.2 × 10⁻⁴
move right 4 places · number < 1 → n = −4 · M = 7.2
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Worked example 2: entering 6.022 × 10²³

6.022 × 10²³ on a calculator
given: 6.022 × 10²³ · wanted: the keying that enters it as one number

Every mole calculation starts by keying this number in. The EE key (EXP on some models) means "times ten to the".

A common first attempt keys the × 10 out loud: 6.022 × 10 EE 23. Test it.

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Worked example 2: solution

6.022 × 10²³ on a calculator
EE means "times ten to the" · wanted: one number in the machine

A common first attempt

keyed 6.022 × 10 EE 23 → the machine holds 6.022 × 10 × 10²³ = 6.022 × 10²⁴ ✗
EE already supplies the × 10 · keying × 10 again multiplies in an extra ten
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Worked example 2: solution

6.022 × 10²³ on a calculator
EE means "times ten to the" · wanted: one number in the machine
A common first attempt
keyed 6.022 × 10 EE 23 → the machine holds 6.022 × 10 × 10²³ = 6.022 × 10²⁴ ✗
EE already supplies the × 10 · keying × 10 again multiplies in an extra ten
The correct keying
keyed 6.022 EE 23 → display 6.022E23 = 6.022 × 10²³ ✓
the whole number enters as one object: coefficient, then EE, then exponent
Dr. Karmach

Worked example 2: solution

6.022 × 10²³ on a calculator
EE means "times ten to the" · wanted: one number in the machine
A common first attempt
keyed 6.022 × 10 EE 23 → the machine holds 6.022 × 10 × 10²³ = 6.022 × 10²⁴ ✗
EE already supplies the × 10 · keying × 10 again multiplies in an extra ten
The correct keying
keyed 6.022 EE 23 → display 6.022E23 = 6.022 × 10²³ ✓
the whole number enters as one object: coefficient, then EE, then exponent
Read the display back before computing: E23 on the screen is × 10²³. A result ten times too large marks the ×10-before-EE slip.
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Worked example 2: the route on the map

keyed 6.022 EE 23 → display 6.022E23 = 6.022 × 10²³
given: 6.022 × 10²³ · found: the keying 6.022 EE 23

EE enters M and n together. Steps 1 to 3 never run: the display already reads M × 10ⁿ. ✓
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Where this goes wrong

Sign backwards. A number below 1 gets a negative n: 0.00456 = 4.56 × 10⁻³, not 10³.
The ×10-before-EE slip. On a calculator, 6.022 EE 23 is 6.022 × 10²³; keying 6.022 × 10 EE 23 multiplies in an extra ten.
Off-by-one count. Count decimal moves, not zeros: 93,000,000 moves 7 places → 10⁷.
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Practice 2

width of one human hair: 0.0000706 m
given: 0.0000706 m · wanted: the width as M × 10ⁿ m

A human hair is 0.0000706 m wide. What is that width in meters, written in scientific notation?

  1. 7.6 × 10⁻⁵
  2. 7.06 × 10⁵
  3. 7.06 × 10⁻⁴
  4. 7.06 × 10⁻⁵
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Practice 2: answer D

0.0000706 m = 7.06 × 10⁻⁵ m
M = 7.06 · decimal moves 5 places right · number < 1 → n = −5

D: the point moves right past four zeros and the 7, 5 places, and M keeps all three digits. A dropped the zero between 7 and 6: a zero caught between nonzero digits is a digit of M. B flipped the sign: a number below 1 takes a negative n. C counted the four zeros and skipped the 7.

Back to standard: −5 slides the point 5 places left, 7.06 → 0.0000706. ✓
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Practice 2: the route on the map

0.0000706 m = 7.06 × 10⁻⁵ m
given: 0.0000706 m · found: M = 7.06 · n = −5

A plain number below 1: the decimal moves right, so the places come off n. ✓
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Practice 3

one grain of fine sand: 2.0 × 10⁻⁶ g
a pinch: 4.5 × 10³ grains

A pinch of fine sand holds 4.5 × 10³ grains, each of mass 2.0 × 10⁻⁶ g. What is the mass of the pinch, in grams?

  1. 9.0 × 10⁹
  2. 9.0 × 10⁻²
  3. 9.0 × 10⁻³
  4. 9.0 × 10³
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Practice 3 · answer: C

keyed 2.0 EE −6 × 4.5 EE 3 → display 9.0E−3 = 9.0 × 10⁻³ g (answer C)
each number enters as one object · E−3 reads back as × 10⁻³

A keyed the −6 as +6: 2.0 × 10⁶ × 4.5 × 10³ = 9.0 × 10⁹. B keyed × 10 before EE, an extra ten: 2.0 × 10 × 10⁻⁶ × 4.5 × 10³ = 9.0 × 10⁻². D read the display back with the sign dropped: E−3 is 10⁻³, not 10³.

A pinch of sand is a few milligrams: 9.0 × 10⁻³ g = 0.0090 g. ✓
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Practice 3: the route on the map

keyed 2.0 EE −6 × 4.5 EE 3 → display 9.0E−3 = 9.0 × 10⁻³ g
given: 2.0 × 10⁻⁶ g per grain · 4.5 × 10³ grains · found: 9.0 × 10⁻³ g

Each number went in with EE, and the display read straight into Step 4. ✓
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Multiplying and dividing by hand

10⁴ × 10⁻⁷ = 10⁴⁺⁽⁻⁷⁾ = 10⁻³ · 10⁴ ÷ 10⁻⁷ = 10⁴⁻⁽⁻⁷⁾ = 10¹¹
multiply: add the exponents · divide: subtract the exponents · subtracting a negative adds

Coefficients multiply or divide; exponents add or subtract. A coefficient outside 1 to 10 gets its decimal placed again: left adds the places to n, right subtracts them. Plain numbers start at n = 0.

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Worked example 3: a product by hand

(6.0 × 10³)(5.0 × 10⁻⁵)
given: 6.0 × 10³ and 5.0 × 10⁻⁵ · wanted: the product as M × 10ⁿ

Multiply the coefficients and add the exponents. Then write the product in scientific notation.

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Worked example 3: solution

(6.0 × 10³)(5.0 × 10⁻⁵)
given: 6.0 × 10³ and 5.0 × 10⁻⁵ · wanted: M × 10ⁿ

Multiply · coefficients times, exponents added

(6.0 × 5.0) × 10³⁺⁽⁻⁵⁾ = 30. × 10⁻²
  1. has two digits before the point. It is not yet scientific notation.
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Worked example 3: solution

(6.0 × 10³)(5.0 × 10⁻⁵)
given: 6.0 × 10³ and 5.0 × 10⁻⁵ · wanted: M × 10ⁿ
Multiply · coefficients times, exponents added
(6.0 × 5.0) × 10³⁺⁽⁻⁵⁾ = 30. × 10⁻²
Step 1 · Place the decimal so one nonzero digit leads Step 2 · Count the places moved
  1. becomes 3.0: the point moves 1 place left.
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Worked example 3: solution

(6.0 × 10³)(5.0 × 10⁻⁵)
given: 6.0 × 10³ and 5.0 × 10⁻⁵ · wanted: M × 10ⁿ
Multiply · coefficients times, exponents added
(6.0 × 5.0) × 10³⁺⁽⁻⁵⁾ = 30. × 10⁻²
Step 1 · Place the decimal so one nonzero digit leads Step 2 · Count the places moved Step 3 · Sign Step 4 · Write M × 10ⁿ

Moved left adds the place to n: −2 + 1 = −1.

30. × 10⁻² = 3.0 × 10⁻¹
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Worked example 3: solution

(6.0 × 10³)(5.0 × 10⁻⁵)
given: 6.0 × 10³ and 5.0 × 10⁻⁵ · wanted: M × 10ⁿ
Multiply · coefficients times, exponents added
(6.0 × 5.0) × 10³⁺⁽⁻⁵⁾ = 30. × 10⁻²
Step 1 · Place the decimal so one nonzero digit leads Step 2 · Count the places moved Step 3 · Sign Step 4 · Write M × 10ⁿ
30. × 10⁻² = 3.0 × 10⁻¹
A calculator keyed 6.0 EE 3 × 5.0 EE −5 shows 0.3, which is 3.0 × 10⁻¹. ✓
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Worked example 3: the route on the map

(6.0 × 10³)(5.0 × 10⁻⁵) = 30. × 10⁻² = 3.0 × 10⁻¹
given: 6.0 × 10³ and 5.0 × 10⁻⁵ · found: 3.0 × 10⁻¹

The by-hand coefficient, 30., sat outside 1 to 10, so it went back through Steps 1 to 3. Moved left: n goes up by 1. ✓
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Practice 4

6.0 × 10⁻⁷ g pollen per m³ · 1.5 × 10⁻⁹ g per grain · 4.0 × 10² m³ of air
given: pollen mass per cubic meter · mass of one grain · air volume · wanted: number of grains

On a high-pollen day, each cubic meter of outdoor air carries 6.0 × 10⁻⁷ g of pollen. One grain has a mass of 1.5 × 10⁻⁹ g. How many pollen grains are in 4.0 × 10² m³ of that air?

  1. 1.6 × 10⁵
  2. 1.6 × 10⁴
  3. 6.3 × 10⁻⁶
  4. 1.6 × 10³
  5. 1.6 × 10⁻¹³
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Practice 4: answer A

6.0 × 10⁻⁷ g pollen per m³ · 1.5 × 10⁻⁹ g per grain · 4.0 × 10² m³ of air
two moves: pollen mass in the air, then grains in that mass
4.0 × 10² m³ × 6.0 × 10⁻⁷ g/m³ = 24 × 10⁻⁵ g = 2.4 × 10⁻⁴ g
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Practice 4: answer A

6.0 × 10⁻⁷ g pollen per m³ · 1.5 × 10⁻⁹ g per grain · 4.0 × 10² m³ of air
two moves: pollen mass in the air, then grains in that mass
4.0 × 10² m³ × 6.0 × 10⁻⁷ g/m³ = 24 × 10⁻⁵ g = 2.4 × 10⁻⁴ g
2.4 × 10⁻⁴ g ÷ 1.5 × 10⁻⁹ g per grain = 1.6 × 10⁻⁴⁻⁽⁻⁹⁾ = 1.6 × 10⁵ grains (answer A)
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Practice 4: answer A

6.0 × 10⁻⁷ g pollen per m³ · 1.5 × 10⁻⁹ g per grain · 4.0 × 10² m³ of air
two moves: pollen mass in the air, then grains in that mass
4.0 × 10² m³ × 6.0 × 10⁻⁷ g/m³ = 24 × 10⁻⁵ g = 2.4 × 10⁻⁴ g
2.4 × 10⁻⁴ g ÷ 1.5 × 10⁻⁹ g per grain = 1.6 × 10⁻⁴⁻⁽⁻⁹⁾ = 1.6 × 10⁵ grains (answer A)
B moved the decimal in 24 but left n at −5: 2.4 × 10⁻⁵ g gives 1.6 × 10⁴. Keying 1.5 × 10 EE −9 lands there too. C divided the grain's mass by the pollen: 1.5 × 10⁻⁹ ÷ 2.4 × 10⁻⁴ = 6.3 × 10⁻⁶. D moved n the wrong way: 24 × 10⁻⁵ became 2.4 × 10⁻⁶ g, which gives 1.6 × 10³. E subtracted 9 instead of −9: 10⁻⁴⁻⁹ = 10⁻¹³.
Each cubic meter holds 6.0 × 10⁻⁷ ÷ 1.5 × 10⁻⁹ = 400 grains, and 400 m³ × 400 = 1.6 × 10⁵. ✓
Dr. Karmach

Practice 4: the route on the map

6.0 × 10⁻⁷ g/m³ × 4.0 × 10² m³ = 24 × 10⁻⁵ g = 2.4 × 10⁻⁴ g
given: 6.0 × 10⁻⁷ g per m³ · 1.5 × 10⁻⁹ g per grain · 4.0 × 10² m³ · found: 1.6 × 10⁵ grains

The product 24 × 10⁻⁵ went back through Steps 1 to 3. The division needed no repair: 1.6 already lies between 1 and 10. ✓
Dr. Karmach

Check yourself

  1. Write 0.000205 and 6,400,000 in scientific notation, and state the sign of each exponent.
  2. Enter (6.0 × 10⁻³)(3.0 × 10⁵) on your calculator with the EE key, and write the display in proper scientific notation.

These powers of ten are the backbone of every mole, concentration, and atomic-mass calculation ahead.

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2 · Significant Figures

Count the significant figures in any measurement, and round a calculated result with the rule that matches the operation.

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Reading an instrument

The cylinder is marked every 1 mL. The water sits most of the way from 36 to 37: record 36.8 mL. The 3 and 6 are certain; the 8 is estimated.

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Every measurement has three parts

36.8 mL
number: 36.8 · unit: mL · uncertainty: the last digit, 8, is estimated

A measurement reports a number, a unit, and how certain the number is. Two students read the same cylinder: 36.7 mL and 36.9 mL. Which digits agree?

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Every measurement has three parts

36.8 mL
number: 36.8 · unit: mL · uncertainty: the last digit, 8, is estimated

A measurement reports a number, a unit, and how certain the number is. Two students read the same cylinder: 36.7 mL and 36.9 mL. Which digits agree?

36.7 mL · 36.9 mL
3 and 6 agree: certain · the last digit differs: estimated

Every reading ends in one estimated digit.

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A measurement's digits record its certainty

36.8 mL
3, 6 certain · 8 estimated: the true volume lies between 36.7 and 36.9 mL

An instrument reports every digit it can distinguish, plus one estimated digit. Those digits are the significant figures. Writing 36.8 mL states the volume is known to the tenths and no further.

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A better instrument gives more digits

36.8 mL (graduated cylinder)
estimated in the tenths → 3 sig figs
36.82 mL (burette)
estimated in the hundredths → 4 sig figs

A burette marks every 0.1 mL, so its estimate lands in the hundredths. Recording 36.82 mL from a cylinder marked in whole milliliters claims a digit that was never measured.

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Exact numbers

24 tablets  ·  1 kg = 1000 g
counted · defined → no estimated digit → exact, unlimited sig figs
24.31 g
measured: the final 1 is estimated → 4 sig figs

Counted objects and defined relationships are not measurements. Nothing in them is estimated, so they have unlimited significant figures. Only measured values limit a result.

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The method

  1. Nonzero digits always count.
  2. Captive zeros (between nonzero digits) always count.
  3. Leading zeros (before the first nonzero digit) never count.
  4. Trailing zeros count only with a decimal point.
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One map for every sig-fig question

Counting tests each digit of one number. A calculated result takes its rule from the operation, then rounds once. Exact numbers never limit either.

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Guided example: a burette reading

20.50 mL
read from a burette marked every 0.1 mL

A burette delivers acid into a flask. Count the significant figures in the reading. Run the four rules in order.

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Guided example: solution

20.50 mL
read from a burette marked every 0.1 mL

Step 1 · Nonzero digits always count

The 2 and the 5 count.

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Guided example: solution

20.50 mL
read from a burette marked every 0.1 mL
Step 1 · Nonzero digits always count Step 2 · Captive zeros always count

The zero between 2 and 5 counts.

Dr. Karmach

Guided example: solution

20.50 mL
read from a burette marked every 0.1 mL
Step 1 · Nonzero digits always count Step 2 · Captive zeros always count Step 3 · Leading zeros never count

No zero sits in front of the 2. This rule removes nothing.

Dr. Karmach

Guided example: solution

20.50 mL
read from a burette marked every 0.1 mL
Step 1 · Nonzero digits always count Step 2 · Captive zeros always count Step 3 · Leading zeros never count Step 4 · Trailing zeros count only with a decimal point

The final zero follows a decimal point, so it counts.

20.50 mL → 4 sig figs
counted: 2, 0, 5, 0 · no placeholders
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Guided example: solution

20.50 mL
read from a burette marked every 0.1 mL
Step 1 · Nonzero digits always count Step 2 · Captive zeros always count Step 3 · Leading zeros never count Step 4 · Trailing zeros count only with a decimal point
20.50 mL → 4 sig figs
counted: 2, 0, 5, 0 · no placeholders
The burette is marked every 0.1 mL, so its estimate lands in the hundredths: the final 0 is the estimated digit. Writing 20.5 mL would throw a measured digit away. ✓
Dr. Karmach

Guided example: the route on the map

20.50 mL
found: 4 sig figs · counted: 2, 0, 5, 0

Three digit tests did the work: nonzero, captive, and trailing with a decimal point. One number, no calculation: the bottom row stays unlit. ✓
Dr. Karmach

Practice 1

100.50 g
a beaker of water on a top-loading balance

How many significant figures are in the balance reading?

  1. 2
  2. 3
  3. 4
  4. 5
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Practice 1 · answer: D

100.50 g → 5 sig figs (answer D)
nonzero: 1, 5 · captive: the two zeros of 100 · trailing with a decimal point: the final 0

A counted only the nonzero digits: 2. B read the zeros of 100 as placeholders: 3. They sit between the 1 and the 5, so they are captive. C dropped the trailing zero after the decimal point: 4.

The balance reads to the hundredths, so the final 0 is its estimated digit. All five digits were measured. ✓
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Practice 1: the route on the map

100.50 g
found: 5 sig figs · counted: 1, 0, 0, 5, 0

The path of the guided example: nonzero, captive, trailing with a decimal point. No leading zero and no placeholder. ✓
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Worked example 1: a mass from the balance

0.04030 g
read from an analytical balance

An analytical balance reports the mass of a powder sample. Count the significant figures: test each digit against the four rules.

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Worked example 1: solution

0.04030 g
read from an analytical balance

Step 1 · Nonzero digits always count

The 4 and the 3 count.

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Worked example 1: solution

0.04030 g
read from an analytical balance
Step 1 · Nonzero digits always count Step 2 · Captive zeros always count

The zero between 4 and 3 counts.

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Worked example 1: solution

0.04030 g
read from an analytical balance
Step 1 · Nonzero digits always count Step 2 · Captive zeros always count Step 3 · Leading zeros never count

The two zeros in front only locate the decimal point.

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Worked example 1: solution

0.04030 g
read from an analytical balance
Step 1 · Nonzero digits always count Step 2 · Captive zeros always count Step 3 · Leading zeros never count Step 4 · Trailing zeros count only with a decimal point

The number has a decimal point, so the final zero counts.

0.04030 g → 4 sig figs
counted: 4, 0, 3, 0 · not counted: the two leading zeros
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Worked example 1: solution

0.04030 g
read from an analytical balance
Step 1 · Nonzero digits always count Step 2 · Captive zeros always count Step 3 · Leading zeros never count Step 4 · Trailing zeros count only with a decimal point
0.04030 g → 4 sig figs
counted: 4, 0, 3, 0 · not counted: the two leading zeros
In scientific notation the placeholders vanish: 4.030 × 10⁻² g shows exactly the four significant digits.
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Worked example 1: the route on the map

0.04030 g
found: 4 sig figs · counted: 4, 0, 3, 0 · not counted: the two leading zeros

All four digit rules ran on one number. Only the leading zeros were left out. ✓
Dr. Karmach

Worked example 2: a scale with no decimal point

1200 kg
a truck-scale reading, no decimal point

A truck scale reports the mass of a loaded pallet. A common first attempt: four written digits, four significant figures. Test it against the rules.

Dr. Karmach

Worked example 2: solution

1200 kg
a truck-scale reading, no decimal point

Step 1 · Nonzero digits always count

The 1 and the 2 count.

Dr. Karmach

Worked example 2: solution

1200 kg
a truck-scale reading, no decimal point
Step 1 · Nonzero digits always count Step 2 · Captive zeros always count Step 3 · Leading zeros never count

No zero sits between nonzero digits, and none leads. Neither rule applies here.

Dr. Karmach

Worked example 2: solution

1200 kg
a truck-scale reading, no decimal point
Step 1 · Nonzero digits always count Step 2 · Captive zeros always count Step 3 · Leading zeros never count Step 4 · Trailing zeros count only with a decimal point

There is no decimal point. The two zeros are placeholders.

1200 kg → 2 sig figs
counted: 1, 2 · placeholders: 0, 0 · the four-digit count fails Step 4
Dr. Karmach

Worked example 2: solution

1200 kg
a truck-scale reading, no decimal point
Step 1 · Nonzero digits always count Step 2 · Captive zeros always count Step 3 · Leading zeros never count Step 4 · Trailing zeros count only with a decimal point
1200 kg → 2 sig figs
counted: 1, 2 · placeholders: 0, 0 · the four-digit count fails Step 4
Written with a decimal point, the same digits all count:
1200. kg → 4 sig figs  ·  1.20 × 10³ kg → 3 sig figs
the decimal point makes trailing zeros count · the coefficient shows only significant digits
Dr. Karmach

Worked example 2: solution

1200 kg
a truck-scale reading, no decimal point
Step 1 · Nonzero digits always count Step 2 · Captive zeros always count Step 3 · Leading zeros never count Step 4 · Trailing zeros count only with a decimal point
1200 kg → 2 sig figs
counted: 1, 2 · placeholders: 0, 0 · the four-digit count fails Step 4
1200. kg → 4 sig figs  ·  1.20 × 10³ kg → 3 sig figs
the decimal point makes trailing zeros count · the coefficient shows only significant digits
Two sig figs: the thousands digit is certain, the hundreds digit is the estimate. Nothing in 1200 records the tens or ones.
Dr. Karmach

Worked example 2: the route on the map

1200 kg
found: 2 sig figs · counted: 1, 2 · placeholders: 0, 0

With no decimal point, the trailing zeros take the placeholder branch. Only the nonzero digits count. ✓
Dr. Karmach

Take-home: trailing zeros need a decimal point

1200 kg, 1200. kg, and 1.20 × 10³ kg describe the same load with different certainty. To mark a trailing zero significant, write the decimal point or use scientific notation.

Dr. Karmach

Your turn: count the sig figs

measurement sig figs
0.0250 L
305.0 g
8700 m

The decimal point decides every trailing zero.

Dr. Karmach

Your turn: count the sig figs

measurement sig figs
0.0250 L
305.0 g
8700 m

The decimal point decides every trailing zero.

0.0250 L → 3  ·  305.0 g → 4  ·  8700 m → 2
trailing zero after a decimal point counts · captive and trailing count · no decimal point: placeholders
Dr. Karmach

Where this goes wrong

Counting trailing zeros with no decimal point. 2600 kg reads as four sig figs. Step 4 gives two: the zeros only hold place. Written 2600. kg, it has four.
Counting the leading zeros. In 0.0250 L, starting the count at the zeros gives 4 or 5. Leading zeros only locate the decimal point: 3 sig figs.
Dropping the trailing zero after a decimal point. The final zero of 0.0250 L was measured, and the decimal point makes it count: 3 sig figs, not 2.
Counting every written digit. 0.0250 L shows five digits but 3 sig figs. A digit is significant when it was measured, not when it is written.
Dr. Karmach

Practice 2

0.02060 g
the mass of a grain of rice on an analytical balance

How many significant figures does the measurement carry?

  1. 3
  2. 4
  3. 5
  4. 6
Dr. Karmach

Practice 2 · answer: B

0.02060 g → 4 sig figs (answer B)
counted: 2, 0, 6, 0 · not counted: the two leading zeros

The 2 and 6 count, the captive zero between them counts, and the decimal point makes the final zero count. A dropped the trailing zero: 3. C started counting at the first zero after the decimal point: 5. D counted every written digit: 6.

Scientific notation strips the placeholders: 2.060 × 10⁻² g keeps exactly four digits.
Dr. Karmach

Practice 2: the route on the map

0.02060 g
found: 4 sig figs · counted: 2, 0, 6, 0 · not counted: the two leading zeros

The path of worked example 1: all four digit rules, with only the leading zeros left out. ✓
Dr. Karmach

Rounding off

7.8342 → 7.83
first dropped digit 4: below 5, the kept digit stays
0.4267 → 0.43
first dropped digit 6: 5 or more, the kept digit rounds up

A calculator returns more digits than a measurement supports. Keep the significant ones and look at the first digit dropped: below 5, keep; 5 or more, round up.

Dr. Karmach

Multiplication and division: fewest sig figs

4.20 × 1.1 = 4.62 → 4.6
3 sig figs × 2 sig figs → report 2 sig figs

A result can be no more certain than its least certain measurement. For multiplication and division, the answer keeps the fewest sig figs found among the inputs.

Dr. Karmach

Worked example 3: volume of a block

8.5 cm × 4.27 cm × 1.36 cm
given: three measured edges · wanted: the volume, correctly reported

A metal block's three edges are measured. Compute the volume and report it with the correct number of sig figs.

Dr. Karmach

Worked example 3: solution

8.5 cm × 4.27 cm × 1.36 cm
sig figs: 2 · 3 · 3

Count each factor's sig figs

8.5 carries two; 4.27 and 1.36 carry three each. The fewest is two.

Dr. Karmach

Worked example 3: solution

8.5 cm × 4.27 cm × 1.36 cm
sig figs: 2 · 3 · 3
Count each factor's sig figs Multiply, then round to the fewest
8.5 × 4.27 × 1.36 = 49.3612 cm³ (calculator) → 49 cm³
reported to 2 sig figs, set by the 8.5
Dr. Karmach

Worked example 3: solution

8.5 cm × 4.27 cm × 1.36 cm
sig figs: 2 · 3 · 3
Count each factor's sig figs Multiply, then round to the fewest
8.5 × 4.27 × 1.36 = 49.3612 cm³ (calculator) → 49 cm³
reported to 2 sig figs, set by the 8.5
The 8.5 cm edge was estimated in the tenths. Two sig figs is everything those rulers measured; the calculator's extra digits were never measured at all.
Dr. Karmach

Worked example 3: the route on the map

8.5 cm × 4.27 cm × 1.36 cm = 49 cm³
found: 49 cm³ · 2 sig figs, set by the 8.5

Count each factor, keep the fewest sig figs, round once: 49.3612 → 49 cm³. The + or − rule stays unlit. ✓
Dr. Karmach

Practice 3

50 paper clips · 43.18 g
given: 50 identical clips in a box · 43.18 g on a balance · wanted: g per clip

A box of 50 identical paper clips has a mass of 43.18 g. What is the mass of one paper clip, in grams?

  1. 0.8636
  2. 0.9
  3. 2159
  4. 1.158
Dr. Karmach

Practice 3 · answer: A

43.18 g ÷ 50 = 0.8636 g per clip (answer A)
43.18 g: measured, 4 sig figs · 50 clips: counted, exact · fewest among the measured values: 4

B read the count as a measurement with one sig fig: 0.8636 → 0.9. C multiplied: 43.18 × 50 = 2159, heavier than the whole box. D flipped the division: 50 ÷ 43.18 = 1.158 clips per gram.

Counted objects carry no estimated digit, so the 50 never limits. The balance's four sig figs set the answer. ✓
Dr. Karmach

Practice 3: the route on the map

43.18 g ÷ 50 = 0.8636 g
found: 0.8636 g per clip · 4 sig figs, set by the balance

The exact count skips the digit tests. Only 43.18 g is counted, and × or ÷ keeps its four sig figs. ✓
Dr. Karmach

Worked example 4: adding two volumes

108.2 mL + 1.66 mL
graduated cylinder (tenths) + burette (hundredths)

A burette adds 1.66 mL to the 108.2 mL already in a flask. A common first attempt: 1.66 has the fewest sig figs, three, so report 110. mL. Test it.

Dr. Karmach

Worked example 4: solution

108.2 mL + 1.66 mL
graduated cylinder (tenths) + burette (hundredths)

A common first attempt

108.2 + 1.66 = 109.86 → 110. mL
the multiplication rule applied to a sum ✗

Rounding to three sig figs threw away the tenths digit the cylinder measured. Addition and subtraction do not count sig figs.

Dr. Karmach

Worked example 4: solution

108.2 mL + 1.66 mL
graduated cylinder (tenths) + burette (hundredths)
A common first attempt
108.2 + 1.66 = 109.86 → 110. mL
the multiplication rule applied to a sum ✗
Round to the least precise decimal place

The cylinder is estimated in the tenths, the burette in the hundredths. The sum ends where the least precise input ends: the tenths.

108.2 + 1.66 = 109.86 → 109.9 mL
rounded to the tenths, the least precise place given ✓
Dr. Karmach

Worked example 4: solution

108.2 mL + 1.66 mL
graduated cylinder (tenths) + burette (hundredths)
A common first attempt
108.2 + 1.66 = 109.86 → 110. mL
the multiplication rule applied to a sum ✗
Round to the least precise decimal place
108.2 + 1.66 = 109.86 → 109.9 mL
rounded to the tenths, the least precise place given ✓
Four sig figs survive even though one input carried three. Addition sets the answer's last decimal place; the sig-fig count follows from it.
Dr. Karmach

Worked example 4: the route on the map

108.2 mL + 1.66 mL = 109.9 mL
found: 109.9 mL · rounded to the tenths, set by 108.2

A sum takes the place rule, not the sig-fig count. The digit tests in the top row never decide it. ✓
Dr. Karmach

Where the answer stops: the cutoff line

Stack the numbers at the decimal point. The least precise input draws a vertical line; nothing right of the line survives into the answer.

Dr. Karmach

Practice 4

23.06 °C, then 21.4 °C
given: 23.06 °C on a digital probe · 21.4 °C on a glass thermometer · wanted: temperature change

Warm water reads 23.06 °C on a digital probe. After cooling, a glass thermometer reads 21.4 °C. What is the temperature change, in °C?

  1. 1.7
  2. −1.7
  3. −1.66
  4. −1.6
Dr. Karmach

Practice 4 · answer: B

21.4 °C − 23.06 °C = −1.66 °C → −1.7 °C (answer B)
change = final − initial · 21.4 ends at the tenths → round to the tenths

A subtracted backwards, initial minus final: +1.7 °C reads as warming. C used the multiplication rule: 21.4 has three sig figs, so −1.66. A difference keeps places, not counts. D cut off the 6 instead of rounding: a first dropped digit of 6 rounds the tenths up.

The water cooled, so the change is negative. The glass thermometer reads only to the tenths, and so does the change. ✓
Dr. Karmach

Practice 4: the route on the map

21.4 °C − 23.06 °C = −1.7 °C
found: −1.7 °C · rounded to the tenths, set by 21.4

The path of worked example 4: a difference takes the place rule, then rounds once. ✓
Dr. Karmach

Match the rule to the operation

Do: for × and ÷, keep the fewest sig figs.

8.5 × 4.27 × 1.36 = 49 cm³
fewest sig figs among the factors: two ✓

Do not: carry that rule into + and −. Round to the least precise decimal place.

108.2 + 1.66 → 110. mL ✗  ·  109.9 mL ✓
sig-fig count applied to a sum ✗ · a sum rounds to the tenths

Times counts digits; plus counts places.

Dr. Karmach

Mixed operations: one rule per step

  1. Order of operations decides the steps.
  2. Each step's own rule decides what that intermediate is entitled to.
  3. Carry the digits unrounded; round once, at the end, to the tightest entitlement.
Dr. Karmach

Worked example 5: two rules in one calculation

(25.462 g − 25.1 g) ÷ 4.4 mL
mass by difference from two balances · volume from a graduated cylinder

A vial is weighed full on an analytical balance, then empty on a coarser one; the sample it held is made up to 4.4 mL. Compute the mass per milliliter: one rule per step.

Dr. Karmach

Worked example 5: solution

(25.462 g − 25.1 g) ÷ 4.4 mL
subtraction runs first: order of operations sets the steps

Subtract, and mark the entitlement

25.462 − 25.1 = 0.362 g → entitled to the tenths (0.4-level)
25.1 ends at the tenths → the difference holds one sig fig

Do not round yet: carry 0.362 unrounded into the division.

Dr. Karmach

Worked example 5: solution

(25.462 g − 25.1 g) ÷ 4.4 mL
subtraction runs first: order of operations sets the steps
Subtract, and mark the entitlement
25.462 − 25.1 = 0.362 g → entitled to the tenths (0.4-level)
25.1 ends at the tenths → the difference holds one sig fig
Divide, then round once
0.362 ÷ 4.4 = 0.0823 g/mL (calculator) → 0.08 g/mL
rounded once, at the end, to 1 sig fig, the tightest entitlement
Dr. Karmach

Worked example 5: solution

(25.462 g − 25.1 g) ÷ 4.4 mL
subtraction runs first: order of operations sets the steps
Subtract, and mark the entitlement
25.462 − 25.1 = 0.362 g → entitled to the tenths (0.4-level)
25.1 ends at the tenths → the difference holds one sig fig
Divide, then round once
0.362 ÷ 4.4 = 0.0823 g/mL (calculator) → 0.08 g/mL
rounded once, at the end, to 1 sig fig, the tightest entitlement
Subtraction between near-equal readings destroys precision: the answer keeps one digit, though every input carried three or more.
Dr. Karmach

Worked example 5: the route on the map

(25.462 g − 25.1 g) ÷ 4.4 mL = 0.08 g/mL
found: 0.08 g/mL · 1 sig fig, set by the subtraction

Both rules ran, one per step: the place rule on the difference, the fewest-sig-figs rule on the division, one rounding at the end. ✓
Dr. Karmach

Your turn: add three masses

14.55 g + 0.322 g + 2.1 g
three balances, three precisions: where does the cutoff line fall?

Calculator: → reported:

Dr. Karmach

Your turn: add three masses

14.55 g + 0.322 g + 2.1 g
three balances, three precisions: where does the cutoff line fall?

Calculator: → reported:

14.55 + 0.322 + 2.1 = 16.972 → 17.0 g
2.1 ends at the tenths → draw the cutoff line after the tenths
Everything right of the line was never measured in the 2.1 g reading.
Dr. Karmach

Your turn: multiply

3.10 × 4.520
two measured values: count each factor's sig figs first

Calculator: → reported:

Dr. Karmach

Your turn: multiply

3.10 × 4.520
two measured values: count each factor's sig figs first

Calculator: → reported:

3.10 × 4.520 = 14.012 → 14.0
fewest sig figs among the factors: three, from 3.10
The trailing zero in 14.0 counts: it is the third significant figure the 3.10 supports.
Dr. Karmach

Your turn: subtract, then divide

(6.77 − 6.2) ÷ 2.33
subtraction first, division second: each step under its own rule

Difference: → entitlement: → reported:

Dr. Karmach

Your turn: subtract, then divide

(6.77 − 6.2) ÷ 2.33
subtraction first, division second: each step under its own rule

Difference: → entitlement: → reported:

6.77 − 6.2 = 0.57 → entitled to the tenths (0.6-level)
one sig fig territory: carry 0.57 unrounded into the division
Dr. Karmach

Your turn: subtract, then divide

(6.77 − 6.2) ÷ 2.33
subtraction first, division second: each step under its own rule

Difference: → entitlement: → reported:

6.77 − 6.2 = 0.57 → entitled to the tenths (0.6-level)
one sig fig territory: carry 0.57 unrounded into the division
0.57 ÷ 2.33 = 0.2446 → 0.2
rounded once, to 1 sig fig: the subtraction set the limit
The three sig figs in 2.33 never mattered; the subtraction's one-digit entitlement caps the answer.
Dr. Karmach

Practice 5

salt: 20.07 g and 1.9 g, from two balances
all of it dissolved to make 150.0 mL of solution

Two portions of salt, 20.07 g and 1.9 g, are dissolved together to make 150.0 mL of solution. What concentration of salt, in g/mL, should be reported?

  1. 0.147
  2. 0.15
  3. 0.146
  4. 22.0
  5. 0.146467
Dr. Karmach

Practice 5 · answer: C

20.07 + 1.9 = 21.97 g → entitled to the tenths: 3 sig figs
sum: place rule, set by 1.9 · carry 21.97 unrounded
21.97 ÷ 150.0 = 0.146467 → 0.146 g/mL (answer C)
division: fewest sig figs, 3 from the sum vs 4 from 150.0

A rounded the sum to 22.0 before dividing: 22.0 ÷ 150.0 = 0.1467 → 0.147. B used one rule throughout: 1.9 has 2 sig figs, so 0.15. D stopped at the sum: 22.0 g is the salt, not the salt per milliliter. E kept every calculator digit.

The sum rule, not the sig-fig count of 1.9, sets the limit: 21.97 keeps three digits. ✓
Dr. Karmach

Practice 5: the route on the map

(20.07 g + 1.9 g) ÷ 150.0 mL = 0.146 g/mL
found: 0.146 g/mL · 3 sig figs, set by the sum

Place rule on the sum, fewest sig figs on the division. 150.0 carries four: the decimal point makes its trailing zeros count. ✓
Dr. Karmach

Practice 6

empty beaker 49.54 g · beaker with sample 52.4 g
the sample is then dissolved to 25.0 mL of solution

An empty beaker reads 49.54 g on one balance. With a sample of sugar in it, a coarser balance reads 52.4 g. The sample is dissolved in water to a final volume of 25.0 mL. Find the mass of sugar per milliliter of solution, in g/mL.

  1. 0.12
  2. 2.9
  3. 0.114
  4. 8.7
  5. 0.11
Dr. Karmach

Practice 6 · answer: E

52.4 − 49.54 = 2.86 g → entitled to the tenths: 2 sig figs
difference: place rule, set by 52.4 · carry 2.86 unrounded
2.86 ÷ 25.0 = 0.1144 → 0.11 g/mL (answer E)
division: fewest sig figs, 2 from the difference vs 3 from 25.0

A rounded the difference before dividing: 2.9 ÷ 25.0 = 0.116 → 0.12. B stopped at the sample: 2.9 g of sugar, not grams per milliliter. C used the count rule on the subtraction: 52.4 has three sig figs, so 2.86 ÷ 25.0 → 0.114. D flipped the division: 25.0 ÷ 2.86 = 8.7 mL per gram.

The coarser balance ends at the tenths, so the sample mass holds two sig figs, and so does the answer. ✓
Dr. Karmach

Practice 6: the route on the map

(52.4 g − 49.54 g) ÷ 25.0 mL = 0.11 g/mL
found: 0.11 g/mL · 2 sig figs, set by the subtraction

The path of worked example 5: place rule on the difference, fewest sig figs on the division, one rounding at the end. ✓
Dr. Karmach

Check yourself

  1. A balance reads 25.10 g. How many sig figs, and which digit is the estimate?
  2. 4.6 × 1.23 and 4.6 + 1.23: which rule rounds each result, and to what?

These rules follow every measurement through every calculation. Unit conversions chain measurements with exact conversion factors: exact numbers never limit sig figs, so the measurement's certainty sets the answer's.

Dr. Karmach

3 · The SI Unit System

Report every measurement as a number plus a unit, name the five SI base units chemistry uses, and read working and built units like the gram, the milliliter, and g/mL as combinations of them.

Dr. Karmach

One object was the kilogram

From 1889 to 2019, the kilogram was a platinum-iridium cylinder near Paris. Every balance on Earth traced to that one object. Three glass domes kept off the dust.

Dr. Karmach

Every measurement reports three things

21.6 mL
number: 21.6 · unit: mL · uncertainty: the last digit, 6, is the estimate

A measurement states how much, against what standard, and how certain. The number gives the size. The unit names the standard. The last digit carries the uncertainty. Without the unit, the rest means nothing.

Dr. Karmach

A number means nothing without its unit

500 → not a measurement · 500 mg → one aspirin tablet
the unit names what was counted

Two of the three are the number and the unit. The number tells how much; the unit tells of what. Strip the unit and the number carries no information another scientist can use.

Dr. Karmach

One system, five base units

The SI system gives every quantity one agreed base unit. Chemistry leans on five: the meter, the kilogram, the second, the kelvin, and the mole. Results measured anywhere compare directly.

Dr. Karmach

Working units of the lab

1 kg = 1000 g · 1 L = 1000 mL
balances read grams · glassware reads milliliters

A kilogram of reagent rarely sits on a bench. Balances read grams and glassware reads milliliters; each working unit ties to a base unit by a power of ten.

Dr. Karmach

The liter is a built unit

10 cm × 10 cm × 10 cm = 1000 cm³ = 1 L
1 mL = 1 cm³ exactly · 1 L = 1000 mL

Multiplying base units builds new ones. A cube 10 cm on each edge encloses one liter, and the milliliter and the cubic centimeter name the same volume exactly.

Dr. Karmach

Density is a built unit

d = m / V → grams per milliliter → g/mL
two measurements combine into one new unit

Dividing a mass by a volume builds a new unit, the gram per milliliter. The unit itself states the meaning: the grams packed into each milliliter of a substance.

Dr. Karmach

Practice 1

base units: m · kg · s · K · mol
wanted: the base unit for one measured quantity

A pharmacist weighs a powder sample. Which SI base unit matches the quantity being measured?

  1. the kilogram (kg)
  2. the gram (g)
  3. the liter (L)
  4. the meter (m)
Dr. Karmach

Practice 1 · answer: A

weighing → mass → kilogram (kg) (answer A)
the one base unit whose name carries a prefix

B is the working unit of the bench, not the base unit; 1 kg = 1000 g ties every gram reading to the kilogram. C measures volume, the space a sample fills. D measures length.

Name the quantity first, then match the unit: a balance measures mass, and mass takes the kilogram. ✓
Dr. Karmach

Practice 2

four notebook entries: a reading and a note on its unit
wanted: the entry that is right on every count

Which notebook entry is correct?

  1. one paper clip: 1 kg, recorded in the SI base unit of mass
  2. a warm water bath: 310 K, recorded in a built unit
  3. a flask of solution: 250 m, recorded as its volume
  4. a sugar solution: 1.20 g/mL, recorded in a built unit
Dr. Karmach

Practice 2 · answer: D

1.20 g/mL: a density, grams divided by milliliters (answer D)
the unit matches the quantity · the size fits a solution · built from two units

A has the right unit and an absurd size: 1 kg is a bag of sugar, and a paper clip is about a gram. B misnames the kelvin; it is one of the five base units. C reports a length; a volume takes mL or L.

Three tests per entry: the unit matches the quantity, the number fits the object, and base or built is named right. ✓
Dr. Karmach

The method

  1. Name the quantity: mass, length, volume, or a built quantity.
  2. Find the SI equality: a prefix or a build.
  3. Write it as a factor: the given unit cancels.
  4. Check the size: a smaller unit gives a larger count.

Dr. Karmach

Guided example: liters to milliliters

1 L = 1000 mL
given: 1.89 L · wanted: mL

A carton of milk holds 1.89 L. How many milliliters does it hold?

Name the quantity first, then find the SI equality that links the two units.

Dr. Karmach

Guided example: solution

1 L = 1000 mL
given: 1.89 L · wanted: mL

Step 1 · Name the quantity

Liters and milliliters both measure volume. One equality links them.

Dr. Karmach

Guided example: solution

1 L = 1000 mL
given: 1.89 L · wanted: mL
Step 1 · Name the quantity Step 2 · Find the SI equality

The prefix milli- means one thousandth, so the equality is 1 L = 1000 mL.

Dr. Karmach

Guided example: solution

1 L = 1000 mL
given: 1.89 L · wanted: mL
Step 1 · Name the quantity Step 2 · Find the SI equality Step 3 · Write it as a factor

Both orientations equal 1. Only one cancels L:

1000 mL1 L cancels L ✓    1 L1000 mL cancels nothing ✗
1.89 L × 1000 mL1 L = 1.89 × 10³ mL
Dr. Karmach

Guided example: solution

1 L = 1000 mL
given: 1.89 L · wanted: mL
Step 1 · Name the quantity Step 2 · Find the SI equality Step 3 · Write it as a factor
1.89 L × 1000 mL1 L = 1.89 × 10³ mL
Step 4 · Check the size
A milliliter is a thousandth of a liter, so the count grows a thousandfold: 1.89 → 1890. Three sig figs stay: 1.89 × 10³ mL ✓
Dr. Karmach

Guided example: the route on the map

1 L = 1000 mL
given: 1.89 L · found: 1.89 × 10³ mL

Volume to volume takes one prefix equality, 1 L = 1000 mL. No build was needed. ✓
Dr. Karmach

Practice 3

18 mg of iron per tablet
given: 18 mg · wanted: g

A multivitamin tablet lists 18 mg of iron. How many grams of iron is that?

  1. 1.8 × 10⁴
  2. 0.18
  3. 0.018
  4. 18
Dr. Karmach

Practice 3 · answer: C

1 g = 1000 mg
given: 18 mg · wanted: g
18 mg × 1 g1000 mg = 0.018 g (answer C)

A flipped the factor: 18 × 1000 = 1.8 × 10⁴, a count that grew while the unit got larger. B used the centi power, 1 g = 100 mg: 18 ÷ 100 = 0.18. D relabeled the unit without converting: 18 mg is not 18 g.

A gram holds 1000 mg, so the count in grams is a thousand times smaller: 18 → 0.018. Two sig figs stay ✓
Dr. Karmach

Practice 3: the route on the map

1 g = 1000 mg
given: 18 mg · found: 0.018 g

Mass to mass takes one prefix equality, 1 g = 1000 mg, the path of the guided example on a different quantity. ✓
Dr. Karmach

Practice 4

a cube, 1.6 cm on each edge
given: 1.6 cm edge · wanted: mL

A sugar cube measures 1.6 cm on each edge. What volume does it fill, in milliliters?

  1. 4.1
  2. 2.6
  3. 4.8
  4. 4.1 × 10⁻³
Dr. Karmach

Practice 4 · answer: A

V = l × w × h · 1 cm³ = 1 mL
given: 1.6 cm edge · wanted: mL

Two moves: build the volume, then apply the exact identity.

V = 1.6 cm × 1.6 cm × 1.6 cm = 4.1 cm³ × 1 mL1 cm³ = 4.1 mL (answer A)

B squared the edge: 1.6 × 1.6 = 2.6 cm², the area of one face. C multiplied the edge by 3: 1.6 × 3 = 4.8 cm, still a length. D converted to liters: 4.1 cm³ × (1 L / 1000 cm³) = 4.1 × 10⁻³ L, not mL.

A sugar cube is a little larger than a 1 cm cube, so it fills a few milliliters: 4.1 mL. The edge has two sig figs, so the volume keeps two ✓
Dr. Karmach

Practice 4: the route on the map

V = l × w × h · 1 cm³ = 1 mL
given: 1.6 cm edge · found: 4.1 mL

The givens are lengths and the wanted quantity is a volume, so both equalities are builds: length cubed, then 1 cm³ = 1 mL. No prefix was needed. ✓
Dr. Karmach

Practice 5

a bin 40.0 cm × 30.0 cm × 25.0 cm
given: three edges in cm · wanted: L

A plastic storage bin is 40.0 cm long, 30.0 cm wide, and 25.0 cm deep. How many liters does it hold?

  1. 3.00 × 10⁴
  2. 0.0300
  3. 3.00 × 10⁷
  4. 30.0
Dr. Karmach

Practice 5 · answer: D

V = l × w × h · 1 cm³ = 1 mL · 1 L = 1000 mL
given: 40.0 cm, 30.0 cm, 25.0 cm · wanted: L

Three moves: build the volume, rename cm³ as mL, then the prefix equality.

V = 40.0 cm × 30.0 cm × 25.0 cm = 3.00 × 10⁴ cm³ = 3.00 × 10⁴ mL
3.00 × 10⁴ mL × 1 L1000 mL = 30.0 L (answer D)
Dr. Karmach

Practice 5 · answer: D

V = l × w × h · 1 cm³ = 1 mL · 1 L = 1000 mL
given: 40.0 cm, 30.0 cm, 25.0 cm · wanted: L
V = 40.0 cm × 30.0 cm × 25.0 cm = 3.00 × 10⁴ cm³ = 3.00 × 10⁴ mL
3.00 × 10⁴ mL × 1 L1000 mL = 30.0 L (answer D)
A stopped at the built volume: 3.00 × 10⁴ is in mL, not L. B converted the edges to meters: 0.400 × 0.300 × 0.250 = 0.0300 m³, and one cubic meter holds 1000 L. C flipped the liter factor: 3.00 × 10⁴ × 1000 = 3.00 × 10⁷.
A liter is a 10 cm cube. The bin's edges hold 4, 3, and 2.5 of those cubes: 4 × 3 × 2.5 = 30.0 L ✓
Dr. Karmach

Practice 5: the route on the map

V = l × w × h · 1 cm³ = 1 mL · 1 L = 1000 mL
given: 40.0 cm, 30.0 cm, 25.0 cm · found: 30.0 L

The path of Practice 4, one step longer: the built volume lands in mL, and the prefix equality 1 L = 1000 mL carries it to liters. ✓
Dr. Karmach

Practice 6

an acrylic block 5.00 cm × 4.00 cm × 2.50 cm · mass 0.0590 kg
given: three edges and a mass · wanted: density, in g/mL

A block of acrylic plastic measures 5.00 cm × 4.00 cm × 2.50 cm and has a mass of 0.0590 kg. What is its density, in g/mL?

  1. 0.847
  2. 1.18 × 10³
  3. 0.00118
  4. 2.95
  5. 1.18
Dr. Karmach

Practice 6 · answer: E

V = l × w × h · 1 cm³ = 1 mL · 1 kg = 1000 g · d = m ÷ V
given: 5.00 cm × 4.00 cm × 2.50 cm · 0.0590 kg · wanted: g/mL

Three moves: build the volume, convert the mass, build the density.

V = 5.00 cm × 4.00 cm × 2.50 cm = 50.0 cm³ = 50.0 mL  ·  0.0590 kg × 1000 g1 kg = 59.0 g
d = 59.0 g50.0 mL = 1.18 g/mL (answer E)
Dr. Karmach

Practice 6 · answer: E

V = l × w × h · 1 cm³ = 1 mL · 1 kg = 1000 g · d = m ÷ V
given: 5.00 cm × 4.00 cm × 2.50 cm · 0.0590 kg · wanted: g/mL
V = 5.00 cm × 4.00 cm × 2.50 cm = 50.0 cm³ = 50.0 mL  ·  0.0590 kg × 1000 g1 kg = 59.0 g
d = 59.0 g50.0 mL = 1.18 g/mL (answer E)
A flipped the ratio: 50.0 mL ÷ 59.0 g = 0.847 mL/g. B divided by liters: 59.0 g ÷ 0.0500 L = 1.18 × 10³ g/L. C skipped kg → g: 0.0590 ÷ 50.0 = 0.00118 kg/mL. D divided by one face: 59.0 ÷ (5.00 × 4.00) = 2.95 g/cm².
Acrylic sinks in water, 1.00 g/mL, but only just: 1.18 g/mL. Every given has three sig figs ✓
Dr. Karmach

Practice 6: the route on the map

V = l × w × h · 1 cm³ = 1 mL · 1 kg = 1000 g · d = m ÷ V
given: 5.00 cm × 4.00 cm × 2.50 cm · 0.0590 kg · found: 1.18 g/mL

Three builds and one prefix: the volume from three lengths, cm³ renamed as mL, grams from kilograms, then density as mass over volume. ✓
Dr. Karmach

Check yourself

  1. A notebook entry reads "volume of solution: 250." State what is missing, then supply a reasonable unit.
  2. Classify each as base or built: the kelvin, the liter, the gram per milliliter.

Every metric prefix, tera through pico, defines an equality with a base unit. Chaining those equalities converts any measurement into any unit: that skill is dimensional analysis.

Dr. Karmach

4 · Dimensional Analysis

Convert a measurement into any unit by chaining conversion factors, each one picked so the unit before it cancels.

Dr. Karmach

Same number, wrong unit

The Mars Climate Orbiter was lost in 1999. One team reported thruster impulse in pound-seconds and the software read newton-seconds. It flew too low and broke apart.

Dr. Karmach

Old unit to new unit

1 dozen = 12 donuts
one amount, two names · old unit × (new unit / old unit) = new unit

A box holds 2 dozen donuts. The equality converts dozens to donuts:

2 dozen × 12 donuts1 dozen = 24 donuts

How many dozen are 36 donuts?

Dr. Karmach

Old unit to new unit

1 dozen = 12 donuts
one amount, two names · old unit × (new unit / old unit) = new unit

A box holds 2 dozen donuts. The equality converts dozens to donuts:

2 dozen × 12 donuts1 dozen = 24 donuts

How many dozen are 36 donuts?

36 donuts × 1 dozen12 donuts = 3 dozen

Old unit on the bottom, new unit on top. Every conversion works this way.

Dr. Karmach

A conversion factor equals 1

1 m = 100 cm
one length, two names

An equality names one amount two ways. Written as a fraction, top matches bottom, so the fraction equals 1. Multiplying by 1 changes the unit, never the quantity.

Dr. Karmach

Units cancel like symbols in algebra

A unit on top cancels the same unit below. The right factor removes the given unit and leaves the wanted one.

given unit A × wanted unit Bunit A = answer, in unit B
Dr. Karmach

Metric prefixes are equalities

Each prefix defines an equality with any base unit: 1 km = 10³ m, 1 mg = 10⁻³ g, 1 ms = 10⁻³ s. One table covers every metric conversion.

King Henry Died By Drinking Chocolate Milk
kilo · hecto · deka · base · deci · centi · milli: one power of ten per word · beyond this run, the table steps by thousands
Dr. Karmach

The unit plan

Sketch the route from the given unit to the wanted unit before any arithmetic. One conversion factor per arrow. When no single equality links them, the route runs through units in between.

Dr. Karmach

The method

  1. Write the given: number and unit.
  2. Pick the factor that cancels its unit: the given unit goes in the denominator.
  3. Multiply; repeat until the wanted unit survives.
  4. Sense-check the size and the surviving unit.

Dr. Karmach

Guided example: a newborn's mass

Step 1 · Write the given

1 kg = 2.205 lb
given: 7.50 lb · wanted: kg

A newborn weighs 7.50 lb. The hospital chart records mass in kilograms. Express the baby's mass in kilograms.

The old unit is lb. The new unit is kg.

Dr. Karmach

Guided example: solution

1 kg = 2.205 lb
given: 7.50 lb · wanted: kg

One conversion factor is needed.

Step 2 · Pick the factor that cancels its unit

The equality gives two factors. The old unit, lb, goes on the bottom:

1 kg2.205 lb cancels lb ✓    2.205 lb1 kg cancels nothing ✗
Dr. Karmach

Guided example: solution

1 kg = 2.205 lb
given: 7.50 lb · wanted: kg
Step 2 · Pick the factor that cancels its unit Step 3 · Multiply; repeat until the wanted unit survives
7.50 lb × 1 kg2.205 lb = 3.40 kg

kg survives after one factor, so the chain stops.

Dr. Karmach

Guided example: solution

1 kg = 2.205 lb
given: 7.50 lb · wanted: kg
Step 2 · Pick the factor that cancels its unit Step 3 · Multiply; repeat until the wanted unit survives
7.50 lb × 1 kg2.205 lb = 3.40 kg
Step 4 · Sense-check
A kilogram is bigger than a pound, so the count in kilograms is smaller: 7.50 → 3.40. A newborn of about 3.4 kg is typical. ✓
Dr. Karmach

Guided example: the route on the map

1 kg = 2.205 lb
given: 7.50 lb · found: 3.40 kg

One factor, from the equality table. kg survived after one factor, so the chain did not repeat. kg is the bigger unit, so the count dropped. ✓
Dr. Karmach

Practice 1

1 in = 2.54 cm
given: 16.0 in · wanted: cm

A large pizza measures 16.0 in across. How many centimeters across is it?

  1. 6.30
  2. 406
  3. 16.0
  4. 40.6
Dr. Karmach

Practice 1 · answer: D

1 in = 2.54 cm
given: 16.0 in · wanted: cm
16.0 in × 2.54 cm1 in = 40.6 cm (answer D)

A flipped the factor: 16.0 / 2.54 = 6.30. B used 1 in = 25.4 cm, the millimeter number: 16.0 × 25.4 = 406. C relabeled the unit without converting: 16.0. The 2.54 is exact by definition, so the three sig figs of 16.0 carry through.

A centimeter is smaller than an inch, so the count grows by 2.54: 16.0 → 40.6. ✓
Dr. Karmach

Practice 1: the route on the map

1 in = 2.54 cm
given: 16.0 in · found: 40.6 cm

One factor, from the equality table, with inches on the bottom. cm is the smaller unit, so the count grew. ✓
Dr. Karmach

Worked example 1

Step 1 · Write the given

1 m = 100 cm
given: 347 cm · wanted: m

A whiteboard measures 347 cm across. Express the width in meters.

A common first attempt uses the factor written 100 cm over 1 m. Test it.

Dr. Karmach

Worked example 1: solution

1 m = 100 cm
given: 347 cm · wanted: m

One conversion factor is needed.

A common first attempt

347 cm × 100 cm1 m = 34,700 cm²/m ✗

No unit cancels, and the answer is not in meters.

Dr. Karmach

Worked example 1: solution

1 m = 100 cm
given: 347 cm · wanted: m
A common first attempt
347 cm × 100 cm1 m = 34,700 cm²/m ✗
Step 2 · Pick the factor that cancels its unit

Both factors come from the same equality, and both equal 1. Only one cancels the given unit:

1 m100 cm cancels cm ✓    100 cm1 m cancels nothing ✗
Dr. Karmach

Worked example 1: solution

1 m = 100 cm
given: 347 cm · wanted: m
A common first attempt
347 cm × 100 cm1 m = 34,700 cm²/m ✗
Step 2 · Pick the factor that cancels its unit Step 3 · Multiply; repeat until the wanted unit survives

One factor completes the plan: cm cancels, m survives.

347 cm × 1 m100 cm = 3.47 m
Dr. Karmach

Worked example 1: solution

1 m = 100 cm
given: 347 cm · wanted: m
A common first attempt
347 cm × 100 cm1 m = 34,700 cm²/m ✗
Step 2 · Pick the factor that cancels its unit Step 3 · Multiply; repeat until the wanted unit survives
347 cm × 1 m100 cm = 3.47 m
A meter holds 100 cm, so the count in meters must be smaller: 347 → 3.47. The width itself is unchanged. ✓
Dr. Karmach

Worked example 1: the route on the map

1 m = 100 cm
given: 347 cm · found: 3.47 m

One prefix factor, with cm on the bottom. m is the bigger unit, so the count dropped. ✓
Dr. Karmach

Take-home: only one orientation cancels

Do: the given unit in the denominator, so it cancels.

347 cm × (1 m / 100 cm) = 3.47 m
cm cancels · m survives ✓

Do not: the given unit on top. Nothing cancels; the factor is inverted.

347 cm × (100 cm / 1 m) = 34,700 cm²/m
no unit cancels → flip the factor ✗
Dr. Karmach

Worked example 2

Step 1 · Write the given

1 µm = 10⁻⁶ m · 1 mm = 10⁻³ m
given: 45 µm · wanted: mm

A fine human hair measures 45 µm across. Express the width in millimeters.

No single equality links µm to mm. The unit plan runs through the base unit: µm → m → mm.

Dr. Karmach

Worked example 2: solution

1 µm = 10⁻⁶ m · 1 mm = 10⁻³ m
given: 45 µm · wanted: mm · plan: µm → m → mm

Two conversion factors are needed.

Step 2 · Pick the factor that cancels its unit

The prefix equality gives the first factor, with µm in the denominator:

45 µm × 10⁻⁶ m1 µm = 4.5 × 10⁻⁵ m
Dr. Karmach

Worked example 2: solution

1 µm = 10⁻⁶ m · 1 mm = 10⁻³ m
given: 45 µm · wanted: mm · plan: µm → m → mm
Step 2 · Pick the factor that cancels its unit
45 µm × 10⁻⁶ m1 µm = 4.5 × 10⁻⁵ m
Step 3 · Multiply; repeat until the wanted unit survives

The result is in meters, not the wanted millimeters. The second factor cancels m and leaves mm:

45 µm × 10⁻⁶ m1 µm × 1 mm10⁻³ m = 0.045 mm
Dr. Karmach

Worked example 2: solution

1 µm = 10⁻⁶ m · 1 mm = 10⁻³ m
given: 45 µm · wanted: mm · plan: µm → m → mm
Step 2 · Pick the factor that cancels its unit
45 µm × 10⁻⁶ m1 µm = 4.5 × 10⁻⁵ m
Step 3 · Multiply; repeat until the wanted unit survives
45 µm × 10⁻⁶ m1 µm × 1 mm10⁻³ m = 0.045 mm
A millimeter holds 1000 µm, so the count drops by 1000: 45 → 0.045. A hair is thinner than a millimeter. ✓
Dr. Karmach

Worked example 2: the route on the map

1 µm = 10⁻⁶ m · 1 mm = 10⁻³ m
given: 45 µm · found: 0.045 mm

Two prefix factors, through the base unit. After the first, m was left, not the wanted mm, so the chain repeated once. ✓
Dr. Karmach

Your turn: feet to centimeters

1 ft = 12 in · 1 in = 2.54 cm
given: 6.00 ft · wanted: cm

A doorway stands 6.00 ft tall. The unit plan: ft → in → cm.

6.00 ft × 12 in1 ft × cm in = cm

Fill the second factor from 1 in = 2.54 cm, then compute.

Dr. Karmach

Your turn: feet to centimeters

1 ft = 12 in · 1 in = 2.54 cm
given: 6.00 ft · wanted: cm

A doorway stands 6.00 ft tall. The unit plan: ft → in → cm.

6.00 ft × 12 in1 ft × cm in = cm

Fill the second factor from 1 in = 2.54 cm, then compute.

6.00 ft × 12 in1 ft × 2.54 cm1 in = 183 cm
Dr. Karmach

Practice 2

21 mg → kg
given: 21 mg · wanted: kg

A grain of rice has a mass of 21 mg. What is its mass in kilograms?

  1. 2.1 × 10⁻⁵
  2. 0.021
  3. 21
  4. 2.1 × 10⁷
Dr. Karmach

Practice 2 · answer: A

1 mg = 10⁻³ g · 1 kg = 10³ g
given: 21 mg · plan: mg → g → kg
21 mg × 10⁻³ g1 mg × 1 kg10³ g = 2.1 × 10⁻⁵ kg (answer A)

B stopped mid-plan at grams: 21 × 10⁻³ = 0.021 g. C flipped the kilogram factor: 21 × 10⁻³ × 10³ = 21, the starting number again. D flipped both factors: 21 × 10³ × 10³ = 2.1 × 10⁷.

A kilogram holds 10⁶ mg, so the count drops by a million: 21 → 2.1 × 10⁻⁵. Prefix equalities are exact, so the two sig figs of 21 carry through. ✓
Dr. Karmach

Practice 2: the route on the map

1 mg = 10⁻³ g · 1 kg = 10³ g
given: 21 mg · found: 2.1 × 10⁻⁵ kg

Two prefix factors, through the base unit, g. After the first, grams were left, not kilograms, so the chain repeated once. ✓
Dr. Karmach

Cubed units: cube the whole equality

Volume is length × length × length. A cubed unit takes the length equality cubed, number and unit together: (1 m)³ = (100 cm)³, so 1 m³ = 10⁶ cm³.

Dr. Karmach

Worked example 3: cubic meters to cubic centimeters

Step 1 · Write the given

1 m = 100 cm
given: 3.5 m³ · wanted: cm³

A concrete pour measures 3.5 m³. Express the volume in cubic centimeters.

A common first attempt uses the linear factor, 100 cm over 1 m, once. Test it.

Dr. Karmach

Worked example 3: solution

1 m = 100 cm
given: 3.5 m³ · wanted: cm³

One conversion factor is needed, cubed.

A common first attempt

3.5 m³ × 100 cm1 m = 350 m²·cm ✗

m³ is m × m × m. One linear factor cancels one m; two survive, and the answer is not in cm³.

Dr. Karmach

Worked example 3: solution

1 m = 100 cm
given: 3.5 m³ · wanted: cm³
A common first attempt
3.5 m³ × 100 cm1 m = 350 m²·cm ✗
Step 2 · Pick the factor that cancels its unit

Cancelling all three copies of m takes the whole equality cubed, number and unit:

(100 cm)³(1 m)³ = 10⁶ cm³1 m³ cancels m³ ✓
Dr. Karmach

Worked example 3: solution

1 m = 100 cm
given: 3.5 m³ · wanted: cm³
A common first attempt
3.5 m³ × 100 cm1 m = 350 m²·cm ✗
Step 2 · Pick the factor that cancels its unit Step 3 · Multiply; repeat until the wanted unit survives

One cubed factor completes the plan: m³ cancels, cm³ survives.

3.5 m³ × 10⁶ cm³1 m³ = 3.5 × 10⁶ cm³
Dr. Karmach

Worked example 3: solution

1 m = 100 cm
given: 3.5 m³ · wanted: cm³
A common first attempt
3.5 m³ × 100 cm1 m = 350 m²·cm ✗
Step 2 · Pick the factor that cancels its unit Step 3 · Multiply; repeat until the wanted unit survives
3.5 m³ × 10⁶ cm³1 m³ = 3.5 × 10⁶ cm³
A centimeter cube is sugar-cube sized, and a million of them fill one cubic meter. The count grows by 10⁶: 3.5 → 3,500,000. The volume itself is unchanged. ✓
Dr. Karmach

Worked example 3: the route on the map

1 m = 100 cm · (1 m)³ = (100 cm)³
given: 3.5 m³ · found: 3.5 × 10⁶ cm³

One prefix equality, cubed, number and unit together: 1 m³ = 10⁶ cm³. cm³ is the smaller unit, so the count grew. ✓
Dr. Karmach

Practice 3

1 m = 100 cm
given: 7.5 × 10⁵ cm³ · wanted: m³

An aquarium holds 7.5 × 10⁵ cm³ of water. How many cubic meters does it hold?

  1. 7500
  2. 7.5 × 10¹¹
  3. 0.75
  4. 7.5 × 10⁷
Dr. Karmach

Practice 3 · answer: C

1 m = 100 cm · (1 m)³ = (100 cm)³
given: 7.5 × 10⁵ cm³ · wanted: m³
7.5 × 10⁵ cm³ × 1 m³10⁶ cm³ = 0.75 m³ (answer C)

A cubed the unit without cubing the number, dividing by only 100: 7.5 × 10⁵ / 100 = 7500. B pointed the cubed factor the wrong way, so nothing cancels: 7.5 × 10⁵ × 10⁶ = 7.5 × 10¹¹. D used the linear factor, inverted: 7.5 × 10⁵ × 100 = 7.5 × 10⁷.

A cubic meter is a cube one meter on each edge, about refrigerator size. A large aquarium is somewhat smaller: 0.75 m³. The count drops by 10⁶ from cm³ to m³. ✓
Dr. Karmach

Practice 3: the route on the map

1 m = 100 cm · (1 m)³ = (100 cm)³
given: 7.5 × 10⁵ cm³ · found: 0.75 m³

The same cubed prefix equality, pointed the other way: cm³ on the bottom. m³ is the bigger unit, so the count dropped. ✓
Dr. Karmach

Where this goes wrong

Inverting the factor. 347 cm × (100 cm / 1 m) = 34,700 cm²/m. No unit cancels, and the answer is not in meters. If the units do not cancel, the factor is inverted: the correct setup gives 3.47 m.
Stopping mid-plan. The plan µm → m → mm has two arrows. Stopping after one gives 4.5 × 10⁻⁵ m: meters, not the wanted millimeters. The chain ends at 0.045 mm.
Calculating without a plan. On a multi-step chain, write the route first: given unit → … → wanted unit. Each arrow names the factor to pick; a skipped arrow shows up as a unit that will not cancel.
Cubing the unit without cubing the number. 1 m³ = 100 cm³ is false. Cubing 1 m = 100 cm cubes both sides entirely: (1 m)³ = (100 cm)³ = 10⁶ cm³. The un-cubed factor turns 3.5 m³ into 350 cm³ instead of 3.5 × 10⁶ cm³.
Dr. Karmach

Practice 4

1 mL = 10⁻³ L · 1 gal = 3.785 L
given: 2500. mL · wanted: gal

A soft-drink bottle holds 2500. mL. How many gallons does it hold?

  1. 2.500
  2. 0.6605
  3. 9.463
  4. 660.5
Dr. Karmach

Practice 4 · answer: B

1 mL = 10⁻³ L · 1 gal = 3.785 L
given: 2500. mL · plan: mL → L → gal
2500. mL × 10⁻³ L1 mL × 1 gal3.785 L = 0.6605 gal (answer B)

Four sig figs survive: 2500. carries four, and the English–metric factor 3.785 counts too, so nothing limits below four. A stopped mid-plan: 2500. mL is 2.500 L, and liters are not gallons. C flipped the gallon factor: 2500./1000 × 3.785 = 9.463. D treated milliliters as liters: 2500./3.785 = 660.5.

A gallon is nearly four liters. The bottle holds 2.500 L, less than one gallon: 0.6605. ✓
Dr. Karmach

Practice 4: the route on the map

1 mL = 10⁻³ L · 1 gal = 3.785 L
given: 2500. mL · found: 0.6605 gal

A prefix factor to liters, then the gallon equality from the table. Two factors. A gallon is the bigger unit, so the count dropped. ✓
Dr. Karmach

Worked example 4: a rate as a conversion factor

Step 1 · Write the given

1 mL = 10⁻³ L · 1 gal = 3.785 L · 0.62137 mi = 1 km
given: 1500. mL of gasoline · this car: 32.00 mi = 1 gal · wanted: km

A car gets 32.00 miles per gallon. How many kilometers can it travel on 1500. mL of gasoline?

Mileage is an equality for this car: 32.00 mi = 1 gal, a measured rating carrying four sig figs. The unit plan: mL → L → gal → mi → km.

Dr. Karmach

Worked example 4: solution

1 mL = 10⁻³ L · 1 gal = 3.785 L · 32.00 mi = 1 gal · 0.62137 mi = 1 km
given: 1500. mL · plan: mL → L → gal → mi → km

Four conversion factors are needed, one per arrow of the plan.

Step 2 · Pick the factor that cancels its unit

The first arrow removes mL. The prefix equality gives the factor, with mL in the denominator:

1500. mL × 10⁻³ L1 mL = 1.500 L
Dr. Karmach

Worked example 4: solution

1 mL = 10⁻³ L · 1 gal = 3.785 L · 32.00 mi = 1 gal · 0.62137 mi = 1 km
given: 1500. mL · plan: mL → L → gal → mi → km
Step 2 · Pick the factor that cancels its unit
1500. mL × 10⁻³ L1 mL = 1.500 L
Step 3 · Multiply; repeat until the wanted unit survives

Each factor cancels the unit left by the one before. The chain ends when km survives:

1500. mL × 10⁻³ L1 mL × 1 gal3.785 L × 32.00 mi1 gal × 1 km0.62137 mi = 20.41 km
Dr. Karmach

Worked example 4: solution

1 mL = 10⁻³ L · 1 gal = 3.785 L · 32.00 mi = 1 gal · 0.62137 mi = 1 km
given: 1500. mL · plan: mL → L → gal → mi → km
Step 2 · Pick the factor that cancels its unit
1500. mL × 10⁻³ L1 mL = 1.500 L
Step 3 · Multiply; repeat until the wanted unit survives
1500. mL × 10⁻³ L1 mL × 1 gal3.785 L × 32.00 mi1 gal × 1 km0.62137 mi = 20.41 km
1500. mL is 1.5 L, under half a gallon: about 12.68 mi of driving. A kilometer is shorter than a mile, so the count in kilometers reads larger: 20.41. ✓
Dr. Karmach

Worked example 4: the route on the map

1 mL = 10⁻³ L · 1 gal = 3.785 L · 32.00 mi = 1 gal · 0.62137 mi = 1 km
given: 1500. mL · found: 20.41 km

Four factors: a prefix, the gallon equality, the car's mileage, then the mile equality. Only the mileage comes from the problem; it holds for this car alone. ✓
Dr. Karmach

Practice 5

1 gal = 3.785 L · this hose: 12.0 L = 1 min · 1 min = 60 s
given: 5.00 gal bucket · wanted: s to fill

A garden hose delivers 12.0 L per minute. How many seconds does it take to fill a 5.00 gal bucket?

  1. 6.60
  2. 25.0
  3. 1.58
  4. 94.6
Dr. Karmach

Practice 5 · answer: D

1 gal = 3.785 L · 12.0 L = 1 min · 1 min = 60 s
given: 5.00 gal · plan: gal → L → min → s
5.00 gal × 3.785 L1 gal × 1 min12.0 L × 60 s1 min = 94.6 s (answer D)

The flow rate is a measured equality, 12.0 L = 1 min, and it converts liters to minutes. A flipped the gallon factor: 5.00 / 3.785 / 12.0 × 60 = 6.60. B skipped the gallon hop and treated gallons as liters: 5.00 / 12.0 × 60 = 25.0. C stopped at minutes: 5.00 × 3.785 / 12.0 = 1.58, a count of min, not s.

5.00 gal is about 19 L. At 12 L each minute that takes a bit over a minute and a half: 94.6 s. ✓
Dr. Karmach

Practice 5: the route on the map

1 gal = 3.785 L · 12.0 L = 1 min · 1 min = 60 s
given: 5.00 gal · found: 94.6 s

Three factors: the gallon equality, the hose's flow rate from the problem, then 1 min = 60 s from the table. ✓
Dr. Karmach

Practice 6

1 kg = 2.205 lb
given: 46.0 lb child · wanted: mL of liquid per dose

A child weighing 46.0 lb is prescribed amoxicillin at 25.0 mg per kg of body mass. The liquid medicine holds 250. mg per 5.00 mL. How many milliliters is one dose?

  1. 522
  2. 23.0
  3. 2.61 × 10⁴
  4. 50.7
  5. 10.4
Dr. Karmach

Practice 6 · answer: E

1 kg = 2.205 lb · this order: 25.0 mg = 1 kg · this liquid: 250. mg = 5.00 mL
given: 46.0 lb · plan: lb → kg → mg → mL
46.0 lb × 1 kg2.205 lb × 25.0 mg1 kg × 5.00 mL250. mg = 10.4 mL (answer E)

A stopped at milligrams: 46.0 / 2.205 × 25.0 = 522 mg, a mass, not a volume. B treated pounds as kilograms: 46.0 × 25.0 × 5.00 / 250. = 23.0. C flipped the liquid's factor: 522 × 250. / 5.00 = 2.61 × 10⁴. D flipped the pound factor: 46.0 × 2.205 × 25.0 × 5.00 / 250. = 50.7.

The child is about 20.9 kg, so the dose is about 522 mg. Each 5.00 mL carries 250. mg, so the dose is a little over two 5 mL spoonfuls: 10.4 mL. ✓
Dr. Karmach

Practice 6: the route on the map

1 kg = 2.205 lb · 25.0 mg = 1 kg · 250. mg = 5.00 mL
given: 46.0 lb · found: 10.4 mL

Three factors: the pound equality from the table, then two from the problem, the dose per kilogram and the strength of the liquid. ✓
Dr. Karmach

Check yourself

  1. From 1 in = 2.54 cm, write both conversion factors. Which one converts 30.0 cm to inches?
  2. Multiplying by a conversion factor changes the unit but never the amount. What does every conversion factor equal?

Density is the next conversion factor: an equality between a substance's mass and its volume, in grams per milliliter. Molar mass and mole ratios follow. Every one converts on this same rail.

Dr. Karmach

5 · Temperature Scales & Conversions

Convert a temperature reading among Celsius, Fahrenheit, and Kelvin, and handle a temperature difference correctly in any scale.

Dr. Karmach

One temperature, three numbers

A Phoenix forecast says 95. A lab thermometer in the same air reads 35. A gas-law table lists the day as 308. Same afternoon, three scales.

Dr. Karmach

Temperature: how hot or cold

water freezes: 32 °F = 0 °C = 273.15 K
read on a thermometer · three scales, one physical temperature · SI unit: the kelvin (K)

Temperature measures how hot or cold a substance is. Each scale gives the same temperature its own number.

Which is colder: 0 °C or 0 °F?

Dr. Karmach

Temperature: how hot or cold

water freezes: 32 °F = 0 °C = 273.15 K
read on a thermometer · three scales, one physical temperature · SI unit: the kelvin (K)

Temperature measures how hot or cold a substance is. Each scale gives the same temperature its own number.

Which is colder: 0 °C or 0 °F?

0 °C is water's freezing point · 0 °F sits 32 F° below it: 32 °F − 32 F° = 0 °F
0 °F is colder ✓ · a zero on two scales marks two different temperatures
Dr. Karmach

A scale is two choices

water freezes: 0 °C = 32 °F = 273.15 K
water boils: 100 °C = 212 °F = 373.15 K

A temperature scale fixes two things: where its zero sits and how large one degree is. Celsius, Fahrenheit, and Kelvin mark the same physical events with different numbers.

Dr. Karmach

Why Kelvin exists

0 K = −273.15 °C
absolute zero: the coldest possible temperature · no negative kelvins

Kelvin puts its zero at absolute zero, where molecular motion reaches its minimum. Every Kelvin reading is positive. Gas volumes and pressures are proportional to Kelvin temperature, so the gas laws require this scale.

Dr. Karmach

Celsius to Kelvin: shift the zero

K = °C + 273.15 · °C = K − 273.15
25 °C + 273.15 = 298.15 K · 298.15 K − 273.15 = 25 °C

A kelvin and a Celsius degree are the same size. Converting a reading is a single shift: add 273.15 going to Kelvin, subtract it coming back.

Dr. Karmach

Celsius to Fahrenheit: stretch, then shift

°F = 1.8(°C) + 32 · °C = (°F − 32) / 1.8
freezing to boiling: 212 − 32 = 180 F° across 100 C° · 180/100 = 1.8

Fahrenheit degrees are smaller, so the reading is stretched by 1.8 before the zero shifts by 32. Going back reverses the order: subtract 32 first, then divide by 1.8.

Dr. Karmach

The method

  1. Name the scales: given and wanted.
  2. Pick the linking equation.
  3. Solve, one operation at a time: between °F and °C, the 32 shifts last going in, first coming back.
  4. Sense-check against the reference points.
Dr. Karmach

One map for every temperature problem

Every route runs through Celsius. Kelvin is one shift away. Fahrenheit is a stretch and a shift away, in a fixed order. No arrow joins Fahrenheit to Kelvin directly.

Dr. Karmach

Guided example: a weather balloon

Step 1 · Name the scales

°C = K − 273.15
given: 241 K · wanted: °C

A weather balloon's sensor reads 241 K high in the atmosphere. Express the reading in °C.

On the map, find the given scale and the wanted one. Kelvin to Celsius is a single arrow.

Dr. Karmach

Guided example: solution

°C = K − 273.15
given: 241 K · wanted: °C

Step 2 · Pick the linking equation

The arrow from Kelvin to Celsius takes the shift back off: subtract 273.15. Nothing stretches, because a kelvin and a Celsius degree are the same size.

Dr. Karmach

Guided example: solution

°C = K − 273.15
given: 241 K · wanted: °C
Step 2 · Pick the linking equation Step 3 · Solve, one operation at a time
°C = 241 − 273.15 = −32.15 → −32 °C
one subtraction · reported to the ones place of 241
Dr. Karmach

Guided example: solution

°C = K − 273.15
given: 241 K · wanted: °C
Step 2 · Pick the linking equation Step 3 · Solve, one operation at a time
°C = 241 − 273.15 = −32.15 → −32 °C
one subtraction · reported to the ones place of 241
Step 4 · Sense-check
241 K sits below water's freezing point, 273.15 K, so the Celsius reading must be negative: −32 °C. ✓
Dr. Karmach

Guided example: the route on the map

°C = K − 273.15
given: 241 K · found: −32 °C

One arrow, Kelvin to Celsius: subtract 273.15. No 1.8 and no 32 on this route. ✓
Dr. Karmach

Practice 1

°C = K − 273.15
given: 358 K · wanted: °C

A sauna's air sensor logs 358 K. What is this temperature in °C?

  1. 631
  2. 85
  3. 185
  4. 153
Dr. Karmach

Practice 1 · answer: B

°C = 358 − 273.15 = 84.85 → 85 °C (answer B)
one subtraction · reported to the ones place of 358

A added the shift instead of taking it off: 358 + 273.15 = 631.15. C answered in Fahrenheit, the wrong scale: 1.8(84.85) + 32 = 184.73. D stretched by 1.8 on the way to Celsius: 1.8 × 84.85 = 152.73; the 1.8 belongs to Fahrenheit.

358 K sits between water's freezing point (273.15 K) and its boiling point (373.15 K): 85 °C, hot but short of boiling. ✓
Dr. Karmach

Practice 1: the route on the map

°C = K − 273.15
given: 358 K · found: 85 °C

One arrow, Kelvin to Celsius: subtract 273.15. A reading above 273.15 K lands above 0 °C. ✓
Dr. Karmach

Worked example 1

Step 1 · Name the scales

K = °C + 273.15
given: 37.0 °C · wanted: K

A water bath holds a protein sample at 37.0 °C, body temperature. The instrument log records temperatures in kelvins. Express the reading in K.

Dr. Karmach

Worked example 1: solution

K = °C + 273.15
given: 37.0 °C · wanted: K

Step 2 · Pick the linking equation

Celsius to Kelvin is one shift. No stretching, because a kelvin and a Celsius degree are already the same size.

Dr. Karmach

Worked example 1: solution

K = °C + 273.15
given: 37.0 °C · wanted: K
Step 2 · Pick the linking equation Step 3 · Solve, one operation at a time
K = 37.0 + 273.15 = 310.15 → 310.2 K
one addition · reported to the tenths place of 37.0
Dr. Karmach

Worked example 1: solution

K = °C + 273.15
given: 37.0 °C · wanted: K
Step 2 · Pick the linking equation Step 3 · Solve, one operation at a time
K = 37.0 + 273.15 = 310.15 → 310.2 K
one addition · reported to the tenths place of 37.0
Step 4 · Sense-check
Body temperature sits between freezing (273.15 K) and boiling (373.15 K), nearer the freezing end: 310.2 K. ✓ The shift moved the number, not the warmth.
Dr. Karmach

Worked example 1: the route on the map

K = °C + 273.15
given: 37.0 °C · found: 310.2 K

One arrow, Celsius to Kelvin: add 273.15. The degrees are the same size, so nothing stretches. ✓
Dr. Karmach

Worked example 2

Step 1 · Name the scales

°F = 1.8(°C) + 32
given: 35.0 °C · wanted: °F

The Phoenix thermometer reads 35.0 °C, and the forecast graphic wants Fahrenheit.

A common first attempt shifts before it stretches: add the 32 first. Test it.

Dr. Karmach

Worked example 2: solution

°F = 1.8(°C) + 32
given: 35.0 °C · wanted: °F

A common first attempt

(35.0 + 32) × 1.8 = 120.6 °F ✗
the 32 got stretched along with the reading

The 32 is already in Fahrenheit-sized degrees. Only the reading gets stretched.

Dr. Karmach

Worked example 2: solution

°F = 1.8(°C) + 32
given: 35.0 °C · wanted: °F
A common first attempt
(35.0 + 32) × 1.8 = 120.6 °F ✗
the 32 got stretched along with the reading
Step 2 · Pick the linking equation Step 3 · Solve, one operation at a time
°F = 1.8(35.0) + 32 = 63.0 + 32 = 95.0 °F
stretch: 1.8 × 35.0 = 63.0 · shift: 63.0 + 32 = 95.0 ✓
Dr. Karmach

Worked example 2: solution

°F = 1.8(°C) + 32
given: 35.0 °C · wanted: °F
A common first attempt
(35.0 + 32) × 1.8 = 120.6 °F ✗
the 32 got stretched along with the reading
Step 2 · Pick the linking equation Step 3 · Solve, one operation at a time
°F = 1.8(35.0) + 32 = 63.0 + 32 = 95.0 °F
stretch: 1.8 × 35.0 = 63.0 · shift: 63.0 + 32 = 95.0 ✓
Step 4 · Sense-check
35.0 °C is just under body temperature (37 °C), so °F must land just under 98.6: 95.0. ✓
Dr. Karmach

Worked example 2: the route on the map

°F = 1.8(°C) + 32
given: 35.0 °C · found: 95.0 °F

One arrow, two operations in the arrow's order: × 1.8 first, then + 32. ✓
Dr. Karmach

Take-home: the 32 never stretches

Do: multiply by 1.8 first, then add 32.

1.8(35.0) + 32 = 95.0 °F
stretch first · shift last ✓

Do not: add 32 first.

(35.0 + 32) × 1.8 = 120.6 °F
the shift got stretched with the reading ✗
Dr. Karmach

Your turn: Fahrenheit to Celsius

°C = (°F − 32) / 1.8
given: 68 °F · wanted: °C

A thermostat is set to 68 °F. Coming back to Celsius, the order reverses: the 32 comes off first, then the 1.8 divides out.

°C = (68 − 32) / 1.8 = / 1.8 = °C

Fill both blanks.

Dr. Karmach

Your turn: Fahrenheit to Celsius

°C = (°F − 32) / 1.8
given: 68 °F · wanted: °C

A thermostat is set to 68 °F. Coming back to Celsius, the order reverses: the 32 comes off first, then the 1.8 divides out.

°C = (68 − 32) / 1.8 = / 1.8 = °C

Fill both blanks.

°C = (68 − 32) / 1.8 = 36 / 1.8 = 20. °C
subtract first · divide last · a 20 °C room
Dr. Karmach

A difference is not a reading

rise from 20 °C to 45 °C: ΔT = 45 − 20 = 25 C° = 25 K
the 273.15 shift cancels in the subtraction · in Fahrenheit: 1.8 × 25 = 45 F°

A reading marks a point; a difference measures a gap. Shifting both endpoints by 273.15 leaves the gap unchanged: a Celsius difference is a Kelvin difference, degree for degree.

Dr. Karmach

Where this goes wrong

Adding 273.15 to a Fahrenheit reading. 98.6 °F + 273.15 = 371.75, a number on no scale. The 273.15 shift belongs to Celsius only. Route through Celsius: (98.6 − 32) / 1.8 = 37.0 °C, then 37.0 + 273.15 = 310.15 K.
Stretching by 1.8 on the way to Kelvin. 1.8(25) + 273.15 = 318.15 is wrong; the 1.8 belongs to Fahrenheit. Celsius and Kelvin degrees are the same size: 25 + 273.15 = 298.15 K.
Converting a temperature difference like a reading. A rise of 25 °C is not a rise of 298.15 K. The shift cancels between the two endpoints: a 25 C° rise is a 25 K rise, and 1.8 × 25 = 45 F°.
Dr. Karmach

Practice 2

K = °C + 273.15
given: −78 °C · wanted: K

Dry ice sublimes at −78 °C. What is this temperature in kelvins?

  1. 351
  2. -108
  3. -351
  4. 195
Dr. Karmach

Practice 2 · answer: D

K = −78 + 273.15 = 195.15 → 195 K (answer D)
−78 is known to the ones place · report 195 K

A dropped the minus sign: 78 + 273.15 = 351.15. C subtracted the shift instead of adding it: −78 − 273.15 = −351.15, and negative kelvins do not exist. B built Fahrenheit instead of Kelvin: 1.8(−78) + 32 = −108.4.

Dry ice is cold, but absolute zero is far colder: 195 K sits 78 degrees below freezing (273.15 K) and well above 0 K. Any negative Kelvin answer fails before the arithmetic starts. ✓
Dr. Karmach

Practice 2: the route on the map

K = °C + 273.15
given: −78 °C · found: 195 K

One arrow, Celsius to Kelvin: add 273.15 to the signed reading, −78 + 273.15. ✓
Dr. Karmach

Practice 3

°F = 1.8(°C) + 32 · K = °C + 273.15
given: 223 K · wanted: °F

A cold-test chamber holds a battery pack at 223 K. Its door display reads in °F. What should the display show?

  1. -58
  2. -50
  3. 4
  4. 122
  5. 433
Dr. Karmach

Practice 3 · answer: A

°C = 223 − 273.15 = −50.15 → °F = 1.8(−50.15) + 32 = −58.27 → −58 °F (answer A)
no direct K → °F equation: route through Celsius · shift, then stretch, then shift · ones place from 223

B stopped at Celsius: −50.15, never stretched or shifted into °F. C divided by 1.8, the coming-back move: −50.15 / 1.8 + 32 = 4.14. D dropped the minus sign: 1.8(50.15) + 32 = 122.27. E fed kelvins straight into the Fahrenheit equation: 1.8(223) + 32 = 433.4.

Below −40 the Fahrenheit number is the more negative one: −50 °C lands at −58 °F. Far colder than a kitchen freezer, far above 0 K. ✓
Dr. Karmach

Practice 3: the route on the map

°F = 1.8(°C) + 32 · K = °C + 273.15
given: 223 K · found: −58 °F

No arrow joins Kelvin to Fahrenheit. Move 1: − 273.15. Move 2: × 1.8, then + 32. ✓
Dr. Karmach

Practice 4

°C = (°F − 32) / 1.8 · K = °C + 273.15
given: 250. °F · wanted: K

An autoclave sterilizes lab glassware at 250. °F. What is this temperature in kelvins?

  1. 491
  2. 121
  3. 394
  4. 523
  5. 380
Dr. Karmach

Practice 4 · answer: C

Two moves are needed: Fahrenheit to Celsius, then Celsius to Kelvin.

°C = (250. − 32) / 1.8 = 121.11 · K = 121.11 + 273.15 = 394.26 → 394 K (answer C)
given: 250. °F · subtract 32 first, divide by 1.8 second · ones place from 250.

A never divided by 1.8: 250. − 32 + 273.15 = 491.15. B stopped at Celsius: (250. − 32) / 1.8 = 121.11. D added 273.15 straight to the Fahrenheit reading: 250. + 273.15 = 523.15. E divided before subtracting: 250. / 1.8 − 32 + 273.15 = 380.04.

250. °F tops water's boiling point, 212 °F, so the answer must top 373.15 K: 394 K, about 21 degrees above boiling. ✓
Dr. Karmach

Practice 4: the route on the map

°C = (°F − 32) / 1.8 · K = °C + 273.15
given: 250. °F · found: 394 K

No arrow joins Fahrenheit to Kelvin. Move 1: − 32, then ÷ 1.8. Move 2: + 273.15. ✓
Dr. Karmach

Check yourself

  1. Liquid nitrogen boils at 77 K. Convert the reading to °C, and state why the answer must come out negative.
  2. A reaction mixture warms from 22 °C to 47 °C. Give the temperature change in C°, in K, and in F°.

The gas laws ahead multiply and divide by temperature. Doubling a Kelvin temperature doubles a gas volume; doubling a Celsius reading means nothing. Every gas-law temperature enters in kelvins.

Dr. Karmach

6 · Density as a Conversion Factor

Use a density to convert between the mass and the volume of a material, alone or chained with other conversion factors on one rail.

Dr. Karmach

Same volume, different mass

Three cubes, the same 1 mL of space. Water: 1.00 g. Aluminum: 2.70 g. Lead: 11.34 g. Each material packs its own mass into a milliliter.

Dr. Karmach

Density: mass per milliliter

ethanol 0.789 · water 1.00 · aluminum 2.70 · iron 7.87 · silver 10.5 · gold 19.3
density in g/mL: the mass, in grams, that fills 1 mL of the material

Each material packs a fixed mass into each milliliter. That rate, in grams per milliliter, is its density, a physical property. A measured density identifies the material.

Dr. Karmach

Density = mass ÷ volume

density = mass ÷ volume
solids and liquids: g/mL or g/cm³, with 1 cm³ = 1 mL · gases: g/L

Divide a mass by the volume it fills. The units divide too: grams over milliliters gives g/mL.

A 2.00 cm³ cube of aluminum has a mass of 5.40 g. Find its density.

Dr. Karmach

Density = mass ÷ volume

density = mass ÷ volume
solids and liquids: g/mL or g/cm³, with 1 cm³ = 1 mL · gases: g/L

Divide a mass by the volume it fills. The units divide too: grams over milliliters gives g/mL.

A 2.00 cm³ cube of aluminum has a mass of 5.40 g. Find its density.

d = 5.40 g2.00 cm³ = 2.70 g/cm³, the same as 2.70 g/mL
Dr. Karmach

A density is an equality

19.3 g of gold = 1 mL of gold
density of gold: 19.3 g/mL

Every equality gives a conversion factor. This one converts between mass and volume:

19.3 g Au1 mL Au or 1 mL Au19.3 g Au

Write it so the given unit cancels.

Dr. Karmach

The method

  1. Map the route: given unit → desired unit.
  2. Start with the given.
  3. Write the density fraction so the unit to cancel sits in the denominator.
  4. Multiply and check that only the desired unit survives.
Dr. Karmach

One map for every density problem

Metric factors move along a row. Only the density crosses between mass and volume, written either way up. Mass ÷ volume builds a density from data.

Dr. Karmach

Guided example: glycerol by the milliliter

Step 1 · Map the route

1.26 g glycerol = 1 mL glycerol
given: 500. mL · wanted: g · route: mL → g

A soap maker pours 500. mL of glycerol into a mixing tank. What mass of glycerol goes in?

Every milliliter of glycerol has a mass of 1.26 g.

Dr. Karmach

Guided example: solution

1.26 g glycerol = 1 mL glycerol
given: 500. mL · wanted: g · route: mL → g

One conversion factor is needed. As a rate: each of the 500. milliliters carries 1.26 g, so the tank receives 500 times 1.26 g.

Dr. Karmach

Guided example: solution

1.26 g glycerol = 1 mL glycerol
given: 500. mL · wanted: g · route: mL → g
Step 2 · Start with the given

The given is 500. mL, so the fraction must cancel milliliters.

Dr. Karmach

Guided example: solution

1.26 g glycerol = 1 mL glycerol
given: 500. mL · wanted: g · route: mL → g
Step 2 · Start with the given Step 3 · Write the density fraction

The equality gives two orientations. Only one cancels mL:

1.26 g1 mL cancels mL ✓    1 mL1.26 g cancels nothing ✗
Dr. Karmach

Guided example: solution

1.26 g glycerol = 1 mL glycerol
given: 500. mL · wanted: g · route: mL → g
Step 2 · Start with the given Step 3 · Write the density fraction Step 4 · Multiply and check
500. mL glycerol × 1.26 g glycerol1 mL glycerol = 630. g glycerol
Dr. Karmach

Guided example: solution

1.26 g glycerol = 1 mL glycerol
given: 500. mL · wanted: g · route: mL → g
Step 2 · Start with the given Step 3 · Write the density fraction Step 4 · Multiply and check
500. mL glycerol × 1.26 g glycerol1 mL glycerol = 630. g glycerol
The same tank of water would take 500. g. Glycerol packs a little more into each milliliter: 630. g ✓
Dr. Karmach

Guided example: the route on the map

1.26 g glycerol = 1 mL glycerol
given: 500. mL · found: 630. g

One arrow, mL → g: the density with milliliters on the bottom. ✓
Dr. Karmach

Practice 1

7.85 g steel = 1 cm³ steel
density of steel: 7.85 g/cm³

A steel ball bearing has a volume of 4.20 cm³. What is its mass, in grams?

  1. 0.535
  2. 3.30
  3. 33.0
  4. 1.87
Dr. Karmach

Practice 1 · answer: C

7.85 g steel = 1 cm³ steel
given: 4.20 cm³ · wanted: g · route: cm³ → g
4.20 cm³ steel × 7.85 g steel1 cm³ steel = 33.0 g steel (answer C)

A flipped the fraction: 4.20 ÷ 7.85 = 0.535, and nothing cancels. B slipped a decimal: 4.20 × 7.85 = 33.0, not 3.30. D divided the density by the volume: 7.85 ÷ 4.20 = 1.87, not a mass.

Estimate: about 8 g in each of about 4 cm³ is near 32 g, so 33.0 g fits. ✓
Dr. Karmach

Practice 1: the route on the map

7.85 g steel = 1 cm³ steel
given: 4.20 cm³ · found: 33.0 g

The path of the guided example. A cm³ is a mL, so the same arrow carries cm³ to grams. ✓
Dr. Karmach

Worked example 1: volume from mass

Step 1 · Map the route

19.3 g Au = 1 mL Au
given: 25.0 g · wanted: mL · route: g → mL

A pendant contains 25.0 g of gold. What volume of gold is that?

A common first attempt: multiply by the density fraction as written, 19.3 g over 1 mL. Test the units.

Dr. Karmach

Worked example 1: solution

19.3 g Au = 1 mL Au
given: 25.0 g · wanted: mL · route: g → mL

A common first attempt

25.0 g Au × 19.3 g Au1 mL Au = 483 g²/mL ✗

Nothing cancels, and no quantity carries g²/mL. The fraction is upside down.

Dr. Karmach

Worked example 1: solution

19.3 g Au = 1 mL Au
given: 25.0 g · wanted: mL · route: g → mL
A common first attempt
25.0 g Au × 19.3 g Au1 mL Au = 483 g²/mL ✗
Step 2 · Start with the given Step 3 · Write the density fraction

The given unit is grams, so grams belong in the denominator. Flip the fraction: 1 mL over 19.3 g.

Dr. Karmach

Worked example 1: solution

19.3 g Au = 1 mL Au
given: 25.0 g · wanted: mL · route: g → mL
A common first attempt
25.0 g Au × 19.3 g Au1 mL Au = 483 g²/mL ✗
Step 2 · Start with the given Step 3 · Write the density fraction Step 4 · Multiply and check
25.0 g Au × 1 mL Au19.3 g Au = 1.30 mL Au
Dr. Karmach

Worked example 1: solution

19.3 g Au = 1 mL Au
given: 25.0 g · wanted: mL · route: g → mL
A common first attempt
25.0 g Au × 19.3 g Au1 mL Au = 483 g²/mL ✗
Step 2 · Start with the given Step 3 · Write the density fraction Step 4 · Multiply and check
25.0 g Au × 1 mL Au19.3 g Au = 1.30 mL Au
Gold packs 19.3 g into each milliliter, so 25.0 g fits in barely more than one: 1.30 mL. ✓
Dr. Karmach

Worked example 1: the route on the map

19.3 g Au = 1 mL Au
given: 25.0 g · found: 1.30 mL

One arrow, g → mL: the density flipped, grams on the bottom. The given unit picks the orientation. ✓
Dr. Karmach

Take-home: the units test the setup

25.0 g × 19.3 g1 mL = 483 g²/mL ✗, not a volume
25.0 g × 1 mL19.3 g = 1.30 mL ✓

There is no multiply-or-divide rule to memorize. Write the fraction so the given unit cancels. A flipped fraction leaves units no quantity carries.

Dr. Karmach

Your turn: ethanol

0.789 g ethanol = 1 mL ethanol
given: 50.0 g · wanted: mL

A hand-sanitizer recipe calls for 50.0 g of ethanol, measured out by volume.

50.0 g × mL g = mL

Fill the fraction so grams cancel, then compute.

Dr. Karmach

Your turn: ethanol

0.789 g ethanol = 1 mL ethanol
given: 50.0 g · wanted: mL

A hand-sanitizer recipe calls for 50.0 g of ethanol, measured out by volume.

50.0 g × mL g = mL

Fill the fraction so grams cancel, then compute.

50.0 g × 1 mL0.789 g = 63.4 mL
Dr. Karmach

Where this goes wrong

Flipping the density fraction. 25.0 g × (19.3 g / 1 mL) = 483 g²/mL. Nothing cancels, and no quantity carries g²/mL. Put the unit to cancel in the denominator: 25.0 g × (1 mL / 19.3 g) = 1.30 mL.
Rearranging d = m/V from memory. A misremembered rearrangement gives 1.26 ÷ 500. = 0.00252 g/mL², which is not a mass. No rearranging is needed: start with the given and multiply by the fraction that cancels its unit.
A slipped decimal. A correct setup can still be keyed in wrong: 63.0 g instead of 630. g. Estimate first. 500 mL at about 1.3 g per milliliter is near 650 g, so 63.0 g cannot be right.
Dr. Karmach

Practice 2

10.5 g Ag = 1 mL Ag
density of silver: 10.5 g/mL

A silversmith buys a 170. g silver ingot. What volume, in mL, does the ingot occupy?

  1. 0.0618
  2. 16.2
  3. 1.62
  4. 1.79 × 10³
Dr. Karmach

Practice 2 · answer: B

10.5 g Ag = 1 mL Ag
given: 170. g · wanted: mL · route: g → mL
170. g Ag × 1 mL Ag10.5 g Ag = 16.2 mL Ag (answer B)

A divided the density by the mass: 10.5 ÷ 170. = 0.0618, and its units are not milliliters. C slipped a decimal: 170. ÷ 10.5 = 16.2, not 1.62. D flipped the fraction: 170. × 10.5 = 1.79 × 10³, with units of g²/mL.

Silver packs 10.5 g into each milliliter, so 170. g occupies far fewer milliliters than its grams: 16.2. ✓
Dr. Karmach

Practice 2: the route on the map

10.5 g Ag = 1 mL Ag
given: 170. g · found: 16.2 mL

The path of worked example 1: one arrow, g → mL, grams on the bottom of the density. ✓
Dr. Karmach

Worked example 2: an unknown metal

417 g of metal pellets · submerged, they raise the water level by 53.0 mL
given: 417 g and 53.0 mL · wanted: density, in g/mL

Candidate densities, in g/mL:

aluminum iron copper silver lead
2.70 7.87 8.96 10.5 11.34

A bin of unlabeled gray pellets arrives at a recycling yard. Density identifies the metal.

Build the density from the data, units in place, and match it to the table.

Dr. Karmach

Worked example 2: solution

417 g of metal pellets · 53.0 mL of water displaced
wanted: density, in g/mL

Build the fraction from the data

d = 417 g53.0 mL = 7.87 g/mL

Mass on top, volume underneath, units in place. The surviving unit, g/mL, is a density.

Dr. Karmach

Worked example 2: solution

417 g of metal pellets · 53.0 mL of water displaced
wanted: density, in g/mL
Build the fraction from the data
d = 417 g53.0 mL = 7.87 g/mL
Match the property
aluminum iron copper silver lead
2.70 7.87 8.96 10.5 11.34

Of the candidates, only iron matches 7.87 g/mL. The pellets are iron.

Dr. Karmach

Worked example 2: solution

417 g of metal pellets · 53.0 mL of water displaced
wanted: density, in g/mL
Build the fraction from the data
d = 417 g53.0 mL = 7.87 g/mL
Match the property
aluminum iron copper silver lead
2.70 7.87 8.96 10.5 11.34
The measured fraction is now a conversion factor for these pellets: 7.87 g over 1 mL converts volume to mass; flipped, mass to volume. ✓
Dr. Karmach

Worked example 2: the route on the map

417 g of metal pellets · 53.0 mL of water displaced
found: 7.87 g/mL, iron

No conversion this time. Mass ÷ volume builds the density from data in one move. ✓
Dr. Karmach

Practice 3

109.3 g of metal · water level 21.4 mL → 33.6 mL
given: 109.3 g · two cylinder readings · wanted: g/mL

A 109.3 g piece of scrap metal is lowered into a graduated cylinder of water. The water level rises from 21.4 mL to 33.6 mL. What is the density of the metal, in g/mL?

  1. 8.96
  2. 3.25
  3. 0.112
  4. 5.11
Dr. Karmach

Practice 3 · answer: A

109.3 g of metal · water level 21.4 mL → 33.6 mL
given: 109.3 g · 21.4 mL before · 33.6 mL after · wanted: g/mL
V = 33.6 mL − 21.4 mL = 12.2 mL → d = 109.3 g12.2 mL = 8.96 g/mL (answer A)

B divided by the after reading: 109.3 ÷ 33.6 = 3.25, but that volume counts the water too. C flipped the fraction: 12.2 ÷ 109.3 = 0.112 mL/g, not a density. D divided by the before reading: 109.3 ÷ 21.4 = 5.11, the water alone.

The metal fills only the 12.2 mL the water rose. 8.96 g/mL matches copper. ✓
Dr. Karmach

Practice 3: the route on the map

109.3 g of metal · water level 21.4 mL → 33.6 mL
given: 109.3 g · two readings · found: 8.96 g/mL

Two moves: after − before gives the metal's volume, then mass ÷ volume. ✓
Dr. Karmach

Density inside a longer route

Metric factors convert within mass or within volume. The density is the only factor that crosses between them. Map the route, then chain the factors on one rail.

Dr. Karmach

Worked example 3: kilograms to liters

Step 1 · Map the route

0.789 g ethanol = 1 mL ethanol
given: 2.50 kg · wanted: L · route: kg → g → mL → L

A stockroom order arrives: 2.50 kg of ethanol. The flammables cabinet is labeled in liters. How many liters is this?

The density carries only the g → mL arrow. Metric equalities carry the other two.

Dr. Karmach

Worked example 3: solution

0.789 g ethanol = 1 mL ethanol
given: 2.50 kg · wanted: L · route: kg → g → mL → L

Three conversion factors are needed.

Step 2 · Start with the given Step 3 · Write the density fraction

The metric factor converts kilograms to grams. The density fraction, written 1 mL over 0.789 g, then cancels grams.

Dr. Karmach

Worked example 3: solution

0.789 g ethanol = 1 mL ethanol
given: 2.50 kg · wanted: L · route: kg → g → mL → L
Step 2 · Start with the given Step 3 · Write the density fraction Step 4 · Multiply and check
2.50 kg × 1000 g1 kg × 1 mL0.789 g × 1 L1000 mL = 3.17 L
Dr. Karmach

Worked example 3: solution

0.789 g ethanol = 1 mL ethanol
given: 2.50 kg · wanted: L · route: kg → g → mL → L
Step 2 · Start with the given Step 3 · Write the density fraction Step 4 · Multiply and check
2.50 kg × 1000 g1 kg × 1 mL0.789 g × 1 L1000 mL = 3.17 L
Ethanol is lighter than water. Water would give exactly 2.50 L; ethanol spreads the same mass over 3.17 L. ✓
Dr. Karmach

Worked example 3: the route on the map

0.789 g ethanol = 1 mL ethanol
given: 2.50 kg · found: 3.17 L

Three moves: kg → g, the density down to mL, then mL → L. Only the middle arrow crosses from mass to volume. ✓
Dr. Karmach

Practice 4

1 gal = 3.785 L · 1.84 g acid = 1 mL acid
given: 3.00 gal of concentrated sulfuric acid · wanted: kg

A stockroom receives 3.00 gal of concentrated sulfuric acid, density 1.84 g/mL. What mass, in kilograms, goes on the inventory sheet?

  1. 6.17
  2. 20,900
  3. 0.0209
  4. 20.9
  5. 1.46
Dr. Karmach

Practice 4 · answer: D

1 gal = 3.785 L · 1.84 g acid = 1 mL acid
given: 3.00 gal · wanted: kg · route: gal → L → mL → g → kg
3.00 gal × 3.785 L1 gal × 1000 mL1 L × 1.84 g1 mL × 1 kg1000 g = 20.9 kg (answer D)
Dr. Karmach

Practice 4 · answer: D

1 gal = 3.785 L · 1.84 g acid = 1 mL acid
given: 3.00 gal · wanted: kg · route: gal → L → mL → g → kg
3.00 gal × 3.785 L1 gal × 1000 mL1 L × 1.84 g1 mL × 1 kg1000 g = 20.9 kg (answer D)
A flipped the density: 11,355 ÷ 1.84 ÷ 1000 = 6.17. B stopped at grams: 20,893 g is the mass in g, not kg. C skipped L → mL, applying g/mL to 11.355 L: 20.9 g = 0.0209 kg. E flipped the gallon factor: 3.00 ÷ 3.785 × 1000 × 1.84 ÷ 1000 = 1.46.
Water would be 11.4 kg; the acid packs 1.84 times the mass per milliliter: 20.9 kg. ✓
Dr. Karmach

Practice 4: the route on the map

1 gal = 3.785 L · 1.84 g acid = 1 mL acid
given: 3.00 gal · found: 20.9 kg

Four moves on one rail: gal → L → mL along the volume row, the density up to grams, then g → kg. ✓
Dr. Karmach

Practice 5

2.70 g aluminum = 1 cm³ aluminum · 0.740 g gasoline = 1 mL gasoline
given: 0.250 L of aluminum · wanted: mL of gasoline

What volume of gasoline, in mL, has the same mass as a 0.250 L block of aluminum?

  1. 675
  2. 0.912
  3. 250.
  4. 68.5
  5. 912
Dr. Karmach

Practice 5 · answer: E

2.70 g aluminum = 1 cm³ aluminum · 0.740 g gasoline = 1 mL gasoline
given: 0.250 L aluminum · wanted: mL gasoline · route: L → cm³ → g → mL

Three conversion factors are needed. The aluminum's mass is also the gasoline's mass.

0.250 L × 1000 cm³1 L × 2.70 g1 cm³ = 675 g → 675 g × 1 mL gasoline0.740 g = 912 mL (answer E)
Dr. Karmach

Practice 5 · answer: E

2.70 g aluminum = 1 cm³ aluminum · 0.740 g gasoline = 1 mL gasoline
given: 0.250 L aluminum · wanted: mL gasoline · route: L → cm³ → g → mL
0.250 L × 1000 cm³1 L × 2.70 g1 cm³ = 675 g → 675 g × 1 mL gasoline0.740 g = 912 mL (answer E)
A stopped at the mass: 675 g. B left the volume in liters: 0.250 × 2.70 ÷ 0.740 = 0.912. C used aluminum's density for the gasoline too: 250. mL, but equal masses of different materials fill different volumes. D swapped the densities: 250. × 0.740 ÷ 2.70 = 68.5.
Aluminum is 3.65 times as dense as gasoline (2.70 ÷ 0.740), so the gasoline fills 3.65 times the 250. mL ✓
Dr. Karmach

Practice 5: the route on the map

2.70 g aluminum = 1 cm³ aluminum · 0.740 g gasoline = 1 mL gasoline
given: 0.250 L aluminum · found: 912 mL gasoline

Three moves: L → mL, up to grams with aluminum's density, back down to mL with gasoline's. Two materials, two densities. ✓
Dr. Karmach

Check yourself

  1. Iron: 7.87 g/mL. State the equality this declares, then write the fraction that converts grams of iron to milliliters.
  2. A route runs kg → g → mL → L. Which arrow is the density's, and why can no metric factor replace it?

Molar mass is the next factor of this kind: the grams in one mole of a substance. One fraction on the same rail converts a mass into a count of particles.

Dr. Karmach

Can you…?

  • ☐ write and read numbers in scientific notation?
  • ☐ report measurements and results with the correct significant figures?
  • ☐ convert units with conversion factors, canceling units at each step?
  • ☐ use density as a conversion factor between mass and volume?
  • ☐ convert a temperature among °C, °F, and K, and handle a temperature difference?

If any box stays empty, the practice site has a drill for it. 🧪

Dr. Karmach

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